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Towards Sustainable Lactic Acid Production: Avoiding Gypsum as a Byproduct by using Selective Liquid‐Phase Adsorption

Rübenach, Lukas ; Lins, Jonas ; Koh, Ezra ; Rose, Marcus (2023)
Towards Sustainable Lactic Acid Production: Avoiding Gypsum as a Byproduct by using Selective Liquid‐Phase Adsorption.
In: ChemSusChem, 2019, 12 (15)
doi: 10.26083/tuprints-00024534
Artikel, Zweitveröffentlichung, Postprint

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Kurzbeschreibung (Abstract)

The utilization of biomass is one of the major challenges for the transition from fossil to renewable resources. Often, the separation of the desired product from the reaction mixture is the most energy-intensive step. Liquid-phase adsorption is a promising separation technology that could significantly improve downstream processing in biorefineries. Highly hydrophobic adsorbents were applied for the separation of lactic acid (LA) from aqueous solutions and to avoid the formation of gypsum as a byproduct. High uptakes and selectivity were obtained in single-solute and co-adsorption experiments. Porous hyper-crosslinked polymers (HCP) and polymer-based spherical activated carbon performed best and showed excellent selectivity for the selective removal of LA. Desorption experiments revealed that HCP was the ideal adsorbent for the separation of LA from aqueous solution and enabled the production of gypsum-free LA.

Typ des Eintrags: Artikel
Erschienen: 2023
Autor(en): Rübenach, Lukas ; Lins, Jonas ; Koh, Ezra ; Rose, Marcus
Art des Eintrags: Zweitveröffentlichung
Titel: Towards Sustainable Lactic Acid Production: Avoiding Gypsum as a Byproduct by using Selective Liquid‐Phase Adsorption
Sprache: Englisch
Publikationsjahr: 2 Oktober 2023
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 24 Juni 2019
Ort der Erstveröffentlichung: Weinheim
Verlag: Wiley-VCH
Titel der Zeitschrift, Zeitung oder Schriftenreihe: ChemSusChem
Jahrgang/Volume einer Zeitschrift: 12
(Heft-)Nummer: 15
DOI: 10.26083/tuprints-00024534
URL / URN: https://tuprints.ulb.tu-darmstadt.de/24534
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Herkunft: Zweitveröffentlichungsservice
Kurzbeschreibung (Abstract):

The utilization of biomass is one of the major challenges for the transition from fossil to renewable resources. Often, the separation of the desired product from the reaction mixture is the most energy-intensive step. Liquid-phase adsorption is a promising separation technology that could significantly improve downstream processing in biorefineries. Highly hydrophobic adsorbents were applied for the separation of lactic acid (LA) from aqueous solutions and to avoid the formation of gypsum as a byproduct. High uptakes and selectivity were obtained in single-solute and co-adsorption experiments. Porous hyper-crosslinked polymers (HCP) and polymer-based spherical activated carbon performed best and showed excellent selectivity for the selective removal of LA. Desorption experiments revealed that HCP was the ideal adsorbent for the separation of LA from aqueous solution and enabled the production of gypsum-free LA.

Status: Postprint
URN: urn:nbn:de:tuda-tuprints-245344
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 540 Chemie
Fachbereich(e)/-gebiet(e): 07 Fachbereich Chemie
07 Fachbereich Chemie > Ernst-Berl-Institut
07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie
07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie > Technische Chemie II
Hinterlegungsdatum: 02 Okt 2023 09:50
Letzte Änderung: 19 Feb 2024 09:23
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