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Determination of the controlling parameters for dislocation nucleation in SrTiO3: An investigation by nanoindentation

Wang, Xiaomei ; Liu, Xiaowei ; Li, Yingwei ; Fang, Xufei (2023)
Determination of the controlling parameters for dislocation nucleation in SrTiO3: An investigation by nanoindentation.
In: Journal of the American Ceramic Society, 106 (10)
doi: 10.1111/jace.19218
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

We conduct nanoindentation to investigate dislocation nucleation in SrTiO3 (STO) single crystals with surface orientations of (0 0 1), (0 1 1), and (1 1 1) with loading/unloading rates of 25, 250, and 2500 μN/s. Results reveal that the critical loads (Pc) at which “pop-in” event occurs depend strongly on surface orientations, but slightly related to loading rate. Based on Pc, the critical shear stress that triggers dislocation nucleation was determined by extracting the maximum resolved shear stress (τmax) along the slip systems of STOusing the Hertzian solution. The dislocation activation shear stress (τa) was determined by averaging τmax. The determined τa is 9.0–12.0 GPa, close to the shear strength (∼G/2π) of STO, indicating that homogeneous dislocation nucleation dominates the pop-in events. The consistency of the determined τa demonstrates that the frameworks for nanoindentation pop-in analysis established for metals can be extended to ceramics, whereas the influence of the limited slip systems should be taken into consideration. Additionally, we estimated the activation volume and the activation energy via the statisticalmodel proposed by Schuh et al. The small values of the determined activation volume (0.6–9.8 Å3) and the activation energy (0.13–0.70 eV) indicate that the dislocation nucleation possibly begins from a single-atom migration and local point defects may participate in the dislocation nucleation process. That is, heterogeneous nucleation may exist initially but the homogeneous dislocation nucleation dominates the pop-in events.

Typ des Eintrags: Artikel
Erschienen: 2023
Autor(en): Wang, Xiaomei ; Liu, Xiaowei ; Li, Yingwei ; Fang, Xufei
Art des Eintrags: Bibliographie
Titel: Determination of the controlling parameters for dislocation nucleation in SrTiO3: An investigation by nanoindentation
Sprache: Englisch
Publikationsjahr: 14 August 2023
Ort: Oxford
Verlag: Wiley-Blackwell
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the American Ceramic Society
Jahrgang/Volume einer Zeitschrift: 106
(Heft-)Nummer: 10
DOI: 10.1111/jace.19218
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Kurzbeschreibung (Abstract):

We conduct nanoindentation to investigate dislocation nucleation in SrTiO3 (STO) single crystals with surface orientations of (0 0 1), (0 1 1), and (1 1 1) with loading/unloading rates of 25, 250, and 2500 μN/s. Results reveal that the critical loads (Pc) at which “pop-in” event occurs depend strongly on surface orientations, but slightly related to loading rate. Based on Pc, the critical shear stress that triggers dislocation nucleation was determined by extracting the maximum resolved shear stress (τmax) along the slip systems of STOusing the Hertzian solution. The dislocation activation shear stress (τa) was determined by averaging τmax. The determined τa is 9.0–12.0 GPa, close to the shear strength (∼G/2π) of STO, indicating that homogeneous dislocation nucleation dominates the pop-in events. The consistency of the determined τa demonstrates that the frameworks for nanoindentation pop-in analysis established for metals can be extended to ceramics, whereas the influence of the limited slip systems should be taken into consideration. Additionally, we estimated the activation volume and the activation energy via the statisticalmodel proposed by Schuh et al. The small values of the determined activation volume (0.6–9.8 Å3) and the activation energy (0.13–0.70 eV) indicate that the dislocation nucleation possibly begins from a single-atom migration and local point defects may participate in the dislocation nucleation process. That is, heterogeneous nucleation may exist initially but the homogeneous dislocation nucleation dominates the pop-in events.

Freie Schlagworte: activation energy, activation volume, dislocation nucleation, nanoindentation pop-in, strontium titanate
Zusätzliche Informationen:

This article also appears in: Editor’s Choice JACerS 2023

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 15 Aug 2023 07:44
Letzte Änderung: 19 Jul 2024 10:48
PPN: 510630812
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