Elvers, Benedict J. ; Pätsch, Sebastian ; Bandaru, Siva S. M. ; Krewald, Vera ; Schulzke, Carola ; Fischer, Christian (2023)
Fine‐Tuning Redox Properties of Heteroleptic Molybdenum Complexes through Ligand‐Ligand‐Cooperativity.
In: Angewandte Chemie International Edition, 2023, 62 (25)
doi: 10.26083/tuprints-00024321
Artikel, Zweitveröffentlichung, Verlagsversion
Kurzbeschreibung (Abstract)
Heteroleptic molybdenum complexes bearing 1,5‐diaza‐3,7‐diphosphacyclooctane (P₂N₂) and non‐innocent dithiolene ligands were synthesized and electrochemically characterized. The reduction potentials of the complexes were found to be fine‐tuned by a synergistic effect identified by DFT calculations as ligand‐ligand cooperativity via non‐covalent interactions. This finding is supported by electrochemical studies combined with UV/Vis spectroscopy and temperature‐dependent NMR spectroscopy. The observed behavior is reminiscent of enzymatic redox modulation using second ligand sphere effects.
| Typ des Eintrags: | Artikel | ||||
|---|---|---|---|---|---|
| Erschienen: | 2023 | ||||
| Autor(en): | Elvers, Benedict J. ; Pätsch, Sebastian ; Bandaru, Siva S. M. ; Krewald, Vera ; Schulzke, Carola ; Fischer, Christian | ||||
| Art des Eintrags: | Zweitveröffentlichung | ||||
| Titel: | Fine‐Tuning Redox Properties of Heteroleptic Molybdenum Complexes through Ligand‐Ligand‐Cooperativity | ||||
| Sprache: | Englisch | ||||
| Publikationsjahr: | 2023 | ||||
| Ort: | Darmstadt | ||||
| Publikationsdatum der Erstveröffentlichung: | 2023 | ||||
| Verlag: | Wiley-VCH | ||||
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Angewandte Chemie International Edition | ||||
| Jahrgang/Volume einer Zeitschrift: | 62 | ||||
| (Heft-)Nummer: | 25 | ||||
| Kollation: | 5 Seiten | ||||
| DOI: | 10.26083/tuprints-00024321 | ||||
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/24321 | ||||
| Zugehörige Links: | |||||
| Herkunft: | Zweitveröffentlichung DeepGreen | ||||
| Kurzbeschreibung (Abstract): | Heteroleptic molybdenum complexes bearing 1,5‐diaza‐3,7‐diphosphacyclooctane (P₂N₂) and non‐innocent dithiolene ligands were synthesized and electrochemically characterized. The reduction potentials of the complexes were found to be fine‐tuned by a synergistic effect identified by DFT calculations as ligand‐ligand cooperativity via non‐covalent interactions. This finding is supported by electrochemical studies combined with UV/Vis spectroscopy and temperature‐dependent NMR spectroscopy. The observed behavior is reminiscent of enzymatic redox modulation using second ligand sphere effects. |
||||
| Alternatives oder übersetztes Abstract: |
|
||||
| Freie Schlagworte: | Ligand-Ligand Cooperativity, Non-Innocence Ligands, Noncovalent Interactions, Redox Chemistry | ||||
| ID-Nummer: | e202303151 | ||||
| Status: | Verlagsversion | ||||
| URN: | urn:nbn:de:tuda-tuprints-243213 | ||||
| Zusätzliche Informationen: | Dedicated to Professor Joachim Heinicke valuing his lifetime achievement in phosphorous and nitrogen-based chemistry. |
||||
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Theoretische Chemie (am 07.02.2024 umbenannt in Quantenchemie) |
||||
| Hinterlegungsdatum: | 04 Aug 2023 12:08 | ||||
| Letzte Änderung: | 07 Aug 2023 05:16 | ||||
| PPN: | |||||
| Zugehörige Links: | |||||
| Export: | |||||
| Suche nach Titel in: | TUfind oder in Google | ||||
 |
Frage zum Eintrag |
Optionen (nur für Redakteure)
 |
Redaktionelle Details anzeigen |
Drucken
Impressum