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Radial Alignment of Carbon Nanotubes via Dead‐End Filtration

Rust, Christian ; Schill, Elias ; Garrity, Oisín ; Spari, Manuel ; Li, Han ; Bacher, Andreas ; Guttmann, Markus ; Reich, Stephanie ; Flavel, Benjamin S. (2023)
Radial Alignment of Carbon Nanotubes via Dead‐End Filtration.
In: Small : nano micro, 2023, 19 (19)
doi: 10.26083/tuprints-00024309
Artikel, Zweitveröffentlichung, Verlagsversion

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Kurzbeschreibung (Abstract)

Dead‐end filtration is a facile method to globally align single wall carbon nanotubes (SWCNTs) in large area films with a 2D order parameter, S2D, approaching unity. Uniaxial alignment has been achieved using pristine and hot‐embossed membranes but more sophisticated geometries have yet to be investigated. In this work, three different patterns with radial symmetry and an area of 3.8 cm² are created. Two of these patterns are replicated by the filtered SWCNTs and S2D values of ≈0.85 are obtained. Each of the radially aligned SWCNT films is characterized by scanning cross‐polarized microscopy in reflectance and laser imaging in transmittance with linear, radial, and azimuthal polarized light fields. The former is used to define a novel indicator akin to the 2D order parameter using Malu's law, yielding 0.82 for the respective film. The films are then transferred to a flexible printed circuit board and terminal two‐probe electrical measurements are conducted to explore the potential of those new alignment geometries.

Typ des Eintrags: Artikel
Erschienen: 2023
Autor(en): Rust, Christian ; Schill, Elias ; Garrity, Oisín ; Spari, Manuel ; Li, Han ; Bacher, Andreas ; Guttmann, Markus ; Reich, Stephanie ; Flavel, Benjamin S.
Art des Eintrags: Zweitveröffentlichung
Titel: Radial Alignment of Carbon Nanotubes via Dead‐End Filtration
Sprache: Englisch
Publikationsjahr: 2023
Ort: Darmstadt
Publikationsdatum der Erstveröffentlichung: 2023
Verlag: Wiley-VCH
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Small : nano micro
Jahrgang/Volume einer Zeitschrift: 19
(Heft-)Nummer: 19
Kollation: 9 Seiten
DOI: 10.26083/tuprints-00024309
URL / URN: https://tuprints.ulb.tu-darmstadt.de/24309
Zugehörige Links:
Herkunft: Zweitveröffentlichung DeepGreen
Kurzbeschreibung (Abstract):

Dead‐end filtration is a facile method to globally align single wall carbon nanotubes (SWCNTs) in large area films with a 2D order parameter, S2D, approaching unity. Uniaxial alignment has been achieved using pristine and hot‐embossed membranes but more sophisticated geometries have yet to be investigated. In this work, three different patterns with radial symmetry and an area of 3.8 cm² are created. Two of these patterns are replicated by the filtered SWCNTs and S2D values of ≈0.85 are obtained. Each of the radially aligned SWCNT films is characterized by scanning cross‐polarized microscopy in reflectance and laser imaging in transmittance with linear, radial, and azimuthal polarized light fields. The former is used to define a novel indicator akin to the 2D order parameter using Malu's law, yielding 0.82 for the respective film. The films are then transferred to a flexible printed circuit board and terminal two‐probe electrical measurements are conducted to explore the potential of those new alignment geometries.

Freie Schlagworte: 1D crystals, hot‐embossing, membranes, optical limiters, polarizers, terahertz spectroscopy, thin films
ID-Nummer: 2207684
Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-243094
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 530 Physik
600 Technik, Medizin, angewandte Wissenschaften > 600 Technik
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Molekulare Nanostrukturen
Hinterlegungsdatum: 04 Aug 2023 12:22
Letzte Änderung: 07 Aug 2023 07:20
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