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Enhanced Piezo-Photocatalytic Performance of Na₀.₅Bi₄.₅Ti4O₁₅ by High-Voltage Poling

Lan, Shuang ; Zheng, Mupeng ; Zhuo, Fangping ; Zhu, Mankang ; Hou, Yudong (2023)
Enhanced Piezo-Photocatalytic Performance of Na₀.₅Bi₄.₅Ti4O₁₅ by High-Voltage Poling.
In: Materials, 16 (14)
doi: 10.3390/ma16145122
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

The internal electric field within a piezoelectric material can effectively inhibit the recombination of photogenerated electron–hole pairs, thus serving as a means to enhance photocatalytic efficiency. Herein, we synthesized a Na0.5Bi4.5Ti4O15 (NBT) catalyst by the hydrothermal method and optimized its catalytic performance by simple high-voltage poling. When applying light and mechanical stirring on a 2 kV mm−1 poled NBT sample, almost 100% of Rhodamine B solution could be degraded in 120 min, and the reaction rate constant reached as high as 28.36 × 10−3 min−1, which was 4.2 times higher than that of the unpoled NBT sample. The enhanced piezo-photocatalytic activity is attributed to the poling-enhanced internal electric field, which facilitates the efficient separation and transfer of photogenerated carriers. Our work provides a new option and idea for the development of piezo-photocatalysts for environmental remediation and pollutant treatment

Typ des Eintrags: Artikel
Erschienen: 2023
Autor(en): Lan, Shuang ; Zheng, Mupeng ; Zhuo, Fangping ; Zhu, Mankang ; Hou, Yudong
Art des Eintrags: Bibliographie
Titel: Enhanced Piezo-Photocatalytic Performance of Na₀.₅Bi₄.₅Ti4O₁₅ by High-Voltage Poling
Sprache: Englisch
Publikationsjahr: 20 Juli 2023
Verlag: MDPI
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Materials
Jahrgang/Volume einer Zeitschrift: 16
(Heft-)Nummer: 14
Kollation: 9 Seiten
DOI: 10.3390/ma16145122
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Kurzbeschreibung (Abstract):

The internal electric field within a piezoelectric material can effectively inhibit the recombination of photogenerated electron–hole pairs, thus serving as a means to enhance photocatalytic efficiency. Herein, we synthesized a Na0.5Bi4.5Ti4O15 (NBT) catalyst by the hydrothermal method and optimized its catalytic performance by simple high-voltage poling. When applying light and mechanical stirring on a 2 kV mm−1 poled NBT sample, almost 100% of Rhodamine B solution could be degraded in 120 min, and the reaction rate constant reached as high as 28.36 × 10−3 min−1, which was 4.2 times higher than that of the unpoled NBT sample. The enhanced piezo-photocatalytic activity is attributed to the poling-enhanced internal electric field, which facilitates the efficient separation and transfer of photogenerated carriers. Our work provides a new option and idea for the development of piezo-photocatalysts for environmental remediation and pollutant treatment

Freie Schlagworte: piezo-photocatalysis, Na0.5Bi4.5Ti4O15, poling process, piezoelectric effect
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Artikel-ID: 5122

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 21 Jul 2023 06:46
Letzte Änderung: 27 Nov 2023 07:25
PPN: 509852300
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