Borsatto, João Victor Basolli ; Maciel, Edvaldo Vasconcelos Soares ; Cifuentes, Alejandro ; Lanças, Fernando Mauro (2023)
Applicability and Limitations of a Capillary-LC Column-Switching System Using Hybrid Graphene-Based Stationary Phases.
In: Molecules, 2023, 28 (13)
doi: 10.26083/tuprints-00024253
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
Graphene oxide sheets fixed over silica particles (SiGO) and their modification functionalized with C18 and endcapped (SiGO-C18ec) have been reported as sorbents for extraction and analytical columns in LC. In this study, a SiGO column was selected as the extraction column and a SiGO-C18ec as the analytical column to study the applicability and limitations of a column-switching system composed exclusively of columns packed with graphene-based sorbents. Pyriproxyfen and abamectin B1a were selected as the analytes, and orange-flavored carbonated soft drinks as the matrix. The proposed system could be successfully applied to the pyriproxyfen analysis in a concentration range between 0.5 to 25 µg/mL presenting a linearity of R² = 0.9931 and an intra-day and inter-day accuracy of 82.2–111.4% (RSD < 13.3%) and 95.5–99.8% (RSD < 12.7%), respectively. Furthermore, the matrix composition affected the area observed for the pyriproxyfen: the higher the concentration of orange juice in the soft drink, the higher the pyriproxyfen the signal observed. Additionally, the SiGO extraction column presented a life use of 120 injections for this matrix. In contrast, the proposed system could not apply to the analysis of abamectin B1a, and the SiGO-C18ec analytical column presented significant tailing compared to a similar approach with a C18 analytical column.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2023 |
| Autor(en): | Borsatto, João Victor Basolli ; Maciel, Edvaldo Vasconcelos Soares ; Cifuentes, Alejandro ; Lanças, Fernando Mauro |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Applicability and Limitations of a Capillary-LC Column-Switching System Using Hybrid Graphene-Based Stationary Phases |
| Sprache: | Englisch |
| Publikationsjahr: | 2023 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2023 |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Molecules |
| Jahrgang/Volume einer Zeitschrift: | 28 |
| (Heft-)Nummer: | 13 |
| Kollation: | 14 Seiten |
| DOI: | 10.26083/tuprints-00024253 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/24253 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Graphene oxide sheets fixed over silica particles (SiGO) and their modification functionalized with C18 and endcapped (SiGO-C18ec) have been reported as sorbents for extraction and analytical columns in LC. In this study, a SiGO column was selected as the extraction column and a SiGO-C18ec as the analytical column to study the applicability and limitations of a column-switching system composed exclusively of columns packed with graphene-based sorbents. Pyriproxyfen and abamectin B1a were selected as the analytes, and orange-flavored carbonated soft drinks as the matrix. The proposed system could be successfully applied to the pyriproxyfen analysis in a concentration range between 0.5 to 25 µg/mL presenting a linearity of R² = 0.9931 and an intra-day and inter-day accuracy of 82.2–111.4% (RSD < 13.3%) and 95.5–99.8% (RSD < 12.7%), respectively. Furthermore, the matrix composition affected the area observed for the pyriproxyfen: the higher the concentration of orange juice in the soft drink, the higher the pyriproxyfen the signal observed. Additionally, the SiGO extraction column presented a life use of 120 injections for this matrix. In contrast, the proposed system could not apply to the analysis of abamectin B1a, and the SiGO-C18ec analytical column presented significant tailing compared to a similar approach with a C18 analytical column. |
| Freie Schlagworte: | capillary liquid chromatography, graphene-based materials, packed column, column switching, direct injection, SiGO, SiGO-C18ec |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-242536 |
| Zusätzliche Informationen: | This article belongs to the Special Issue Food Analysis in the 21st Century: Challenges and Possibilities |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Clemens-Schöpf-Institut > Fachgebiet Biochemie 07 Fachbereich Chemie > Clemens-Schöpf-Institut |
| Hinterlegungsdatum: | 14 Jul 2023 11:19 |
| Letzte Änderung: | 02 Aug 2024 12:54 |
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| Suche nach Titel in: | TUfind oder in Google |
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- Applicability and Limitations of a Capillary-LC Column-Switching System Using Hybrid Graphene-Based Stationary Phases. (deposited 14 Jul 2023 11:19) [Gegenwärtig angezeigt]
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