Hock, Sebastian ; Iser, Leonhard ; Lucas, Martin ; Rose, Marcus (2022)
Reaction kinetics of an industrial front‐end acetylene hydrogenation catalyst using the advanced TEMKIN reactor.
In: Chemie Ingenieur Technik, 94 (11)
doi: 10.1002/cite.202200021
Artikel, Bibliographie
Dies ist die neueste Version dieses Eintrags.
Kurzbeschreibung (Abstract)
The front‐end process integration of the selective acetylene hydrogenation provides several advantages over the tail‐end option. But extensive knowledge of the process and reaction kinetics are required. This work combines the ideal conditions of the advanced TEMKIN reactor in a laboratory plant for gradient‐free kinetic analysis of eggshell catalyst under industrially relevant front‐end conditions. With this system an industrial state of the art Pd‐Ag/Al₂O₃ eggshell catalyst is investigated and the temperature dependent data under various feed compositions including information on the formation of C₄‐species are reported.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2022 |
| Autor(en): | Hock, Sebastian ; Iser, Leonhard ; Lucas, Martin ; Rose, Marcus |
| Art des Eintrags: | Bibliographie |
| Titel: | Reaction kinetics of an industrial front‐end acetylene hydrogenation catalyst using the advanced TEMKIN reactor |
| Sprache: | Englisch |
| Publikationsjahr: | 2022 |
| Ort: | Weinheim |
| Verlag: | Wiley-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Chemie Ingenieur Technik |
| Jahrgang/Volume einer Zeitschrift: | 94 |
| (Heft-)Nummer: | 11 |
| DOI: | 10.1002/cite.202200021 |
| Zugehörige Links: | |
| Kurzbeschreibung (Abstract): | The front‐end process integration of the selective acetylene hydrogenation provides several advantages over the tail‐end option. But extensive knowledge of the process and reaction kinetics are required. This work combines the ideal conditions of the advanced TEMKIN reactor in a laboratory plant for gradient‐free kinetic analysis of eggshell catalyst under industrially relevant front‐end conditions. With this system an industrial state of the art Pd‐Ag/Al₂O₃ eggshell catalyst is investigated and the temperature dependent data under various feed compositions including information on the formation of C₄‐species are reported. |
| Freie Schlagworte: | Acetylene hydrogenation, Catalysis, Front‐end, Reaction engineering, TEMKIN reactor |
| Fachbereich(e)/-gebiet(e): | DFG-Sonderforschungsbereiche (inkl. Transregio) DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche 07 Fachbereich Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie > Technische Chemie II DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 1487: Eisen, neu gedacht! |
| Hinterlegungsdatum: | 16 Mai 2023 05:44 |
| Letzte Änderung: | 19 Feb 2024 09:26 |
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Verfügbare Versionen dieses Eintrags
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Reaction Kinetics of an Industrial Front‐End Acetylene Hydrogenation Catalyst Using the Advanced TEMKIN Reactor. (deposited 28 Nov 2022 14:11)
- Reaction kinetics of an industrial front‐end acetylene hydrogenation catalyst using the advanced TEMKIN reactor. (deposited 16 Mai 2023 05:44) [Gegenwärtig angezeigt]
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