Rust, Christian ; Shapturenka, Pavel ; Spari, Manuel ; Jin, Qihao ; Li, Han ; Bacher, Andreas ; Guttmann, Markus ; Zheng, Ming ; Adel, Tehseen ; Walker, Angela R. Hight ; Fagan, Jeffrey A. ; Flavel, Benjamin S. (2023)
The Impact of Carbon Nanotube Length and Diameter on their Global Alignment by Dead‐End Filtration.
In: Small : nano micro, 2023, 19 (10)
doi: 10.26083/tuprints-00023701
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
Dead‐end filtration has proven to effectively prepare macroscopically (3.8 cm²) aligned thin films from solutionbased single‐wall carbon nanotubes (SWCNTs). However, to make this technique broadly applicable, the role of SWCNT length and diameter must be understood. To date, most groups report the alignment of unsorted, large diameter (≈1.4 nm) SWCNTs, but systematic studies on their small diameter are rare (≈0.78 nm). In this work, films with an area of A = 3.81 cm² and a thickness of ≈40 nm are prepared from length‐sorted fractions comprising of small and large diameter SWCNTs, respectively. The alignment is characterized by cross‐polarized microscopy, scanning electron microscopy, absorption and Raman spectroscopy. For the longest fractions (Lavg = 952 nm ± 431 nm, Δ = 1.58 and Lavg = 667 nm ± 246 nm, Δ = 1.55), the 2D order parameter, S2D, values of ≈0.6 and ≈0.76 are reported for the small and large diameter SWCNTs over an area of A = 625 µm², respectively. A comparison of Derjaguin, Landau, Verwey, and Overbeek (DLVO) theory calculations with the aligned domain size is then used to propose a law identifying the required length of a carbon nanotube with a given diameter and zeta potential.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2023 |
| Autor(en): | Rust, Christian ; Shapturenka, Pavel ; Spari, Manuel ; Jin, Qihao ; Li, Han ; Bacher, Andreas ; Guttmann, Markus ; Zheng, Ming ; Adel, Tehseen ; Walker, Angela R. Hight ; Fagan, Jeffrey A. ; Flavel, Benjamin S. |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | The Impact of Carbon Nanotube Length and Diameter on their Global Alignment by Dead‐End Filtration |
| Sprache: | Englisch |
| Publikationsjahr: | 2023 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2023 |
| Verlag: | Wiley-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Small : nano micro |
| Jahrgang/Volume einer Zeitschrift: | 19 |
| (Heft-)Nummer: | 10 |
| Kollation: | 13 Seiten |
| DOI: | 10.26083/tuprints-00023701 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/23701 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Dead‐end filtration has proven to effectively prepare macroscopically (3.8 cm²) aligned thin films from solutionbased single‐wall carbon nanotubes (SWCNTs). However, to make this technique broadly applicable, the role of SWCNT length and diameter must be understood. To date, most groups report the alignment of unsorted, large diameter (≈1.4 nm) SWCNTs, but systematic studies on their small diameter are rare (≈0.78 nm). In this work, films with an area of A = 3.81 cm² and a thickness of ≈40 nm are prepared from length‐sorted fractions comprising of small and large diameter SWCNTs, respectively. The alignment is characterized by cross‐polarized microscopy, scanning electron microscopy, absorption and Raman spectroscopy. For the longest fractions (Lavg = 952 nm ± 431 nm, Δ = 1.58 and Lavg = 667 nm ± 246 nm, Δ = 1.55), the 2D order parameter, S2D, values of ≈0.6 and ≈0.76 are reported for the small and large diameter SWCNTs over an area of A = 625 µm², respectively. A comparison of Derjaguin, Landau, Verwey, and Overbeek (DLVO) theory calculations with the aligned domain size is then used to propose a law identifying the required length of a carbon nanotube with a given diameter and zeta potential. |
| Freie Schlagworte: | 1D crystals, aligned nanomaterials, membranes, polarizers, thin films, zeta potential |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-237019 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften und Maschinenbau 600 Technik, Medizin, angewandte Wissenschaften > 660 Technische Chemie |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft |
| Hinterlegungsdatum: | 12 Mai 2023 09:03 |
| Letzte Änderung: | 15 Mai 2023 06:49 |
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| Suche nach Titel in: | TUfind oder in Google |
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