Fu, Qiang ; Schwarz, Björn ; Ding, Ziming ; Sarapulova, Angelina ; Weidler, Peter G. ; Missyul, Alexander ; Etter, Martin ; Welter, Edmund ; Hua, Weibo ; Knapp, Michael ; Dsoke, Sonia ; Ehrenberg, Helmut (2023)
Guest Ion‐Dependent Reaction Mechanisms of New Pseudocapacitive Mg₃V₄(PO₄)₆/Carbon Composite as Negative Electrode for Monovalent‐Ion Batteries.
In: Advanced Science, 2023, 10 (11)
doi: 10.26083/tuprints-00023742
Artikel, Zweitveröffentlichung, Verlagsversion
 | Es ist eine neuere Version dieses Eintrags verfügbar. |
Kurzbeschreibung (Abstract)
Polyanion‐type phosphate materials, such as M₃V₂(PO₄)₃ (M = Li/Na/K), are promising as insertion‐type negative electrodes for monovalent‐ion batteries including Li/Na/K‐ion batteries (lithium‐ion batteries (LIBs), sodium‐ion batteries (SIBs), and potassium‐ion batteries (PIBs)) with fast charging/discharging and distinct redox peaks. However, it remains a great challenge to understand the reaction mechanism of materials upon monovalent‐ion insertion. Here, triclinic Mg₃V₄(PO₄)₆/carbon composite (MgVP/C) with high thermal stability is synthesized via ball‐milling and carbon‐thermal reduction method and applied as a pseudocapacitive negative electrode in LIBs, SIBs, and PIBs. In operando and ex situ studies demonstrate the guest ion‐dependent reaction mechanisms of MgVP/C upon monovalent‐ion storage due to different sizes. MgVP/C undergoes an indirect conversion reaction to form Mg⁰, V⁰, and Li₃PO₄ in LIBs, while in SIBs/PIBs the material only experiences a solid solution with the reduction of V³⁺ to V²⁺. Moreover, in LIBs, MgVP/C delivers initial lithiation/delithiation capacities of 961/607 mAh g⁻¹ (30/19 Li⁺ ions) for the first cycle, despite its low initial Coulombic efficiency, fast capacity decay for the first 200 cycles, and limited reversible insertion/deinsertion of 2 Na⁺/K⁺ ions in SIBs/PIBs. This work reveals a new pseudocapacitive material and provides an advanced understanding of polyanion phosphate negative material for monovalent‐ion batteries with guest ion‐dependent energy storage mechanisms.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2023 |
| Autor(en): | Fu, Qiang ; Schwarz, Björn ; Ding, Ziming ; Sarapulova, Angelina ; Weidler, Peter G. ; Missyul, Alexander ; Etter, Martin ; Welter, Edmund ; Hua, Weibo ; Knapp, Michael ; Dsoke, Sonia ; Ehrenberg, Helmut |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Guest Ion‐Dependent Reaction Mechanisms of New Pseudocapacitive Mg₃V₄(PO₄)₆/Carbon Composite as Negative Electrode for Monovalent‐Ion Batteries |
| Sprache: | Englisch |
| Publikationsjahr: | 2023 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2023 |
| Verlag: | Wiley-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Advanced Science |
| Jahrgang/Volume einer Zeitschrift: | 10 |
| (Heft-)Nummer: | 11 |
| Kollation: | 12 Seiten |
| DOI: | 10.26083/tuprints-00023742 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/23742 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Polyanion‐type phosphate materials, such as M₃V₂(PO₄)₃ (M = Li/Na/K), are promising as insertion‐type negative electrodes for monovalent‐ion batteries including Li/Na/K‐ion batteries (lithium‐ion batteries (LIBs), sodium‐ion batteries (SIBs), and potassium‐ion batteries (PIBs)) with fast charging/discharging and distinct redox peaks. However, it remains a great challenge to understand the reaction mechanism of materials upon monovalent‐ion insertion. Here, triclinic Mg₃V₄(PO₄)₆/carbon composite (MgVP/C) with high thermal stability is synthesized via ball‐milling and carbon‐thermal reduction method and applied as a pseudocapacitive negative electrode in LIBs, SIBs, and PIBs. In operando and ex situ studies demonstrate the guest ion‐dependent reaction mechanisms of MgVP/C upon monovalent‐ion storage due to different sizes. MgVP/C undergoes an indirect conversion reaction to form Mg⁰, V⁰, and Li₃PO₄ in LIBs, while in SIBs/PIBs the material only experiences a solid solution with the reduction of V³⁺ to V²⁺. Moreover, in LIBs, MgVP/C delivers initial lithiation/delithiation capacities of 961/607 mAh g⁻¹ (30/19 Li⁺ ions) for the first cycle, despite its low initial Coulombic efficiency, fast capacity decay for the first 200 cycles, and limited reversible insertion/deinsertion of 2 Na⁺/K⁺ ions in SIBs/PIBs. This work reveals a new pseudocapacitive material and provides an advanced understanding of polyanion phosphate negative material for monovalent‐ion batteries with guest ion‐dependent energy storage mechanisms. |
| Freie Schlagworte: | in operando synchrotron diffraction, in operando X‐ray absorption spectroscopy, magnetic properties, monovalent‐ion batteries, triclinic Mg₃V₄(PO₄)₆ |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-237429 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 600 Technik, Medizin, angewandte Wissenschaften > 660 Technische Chemie |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > In-Situ Elektronenmikroskopie |
| Hinterlegungsdatum: | 28 Apr 2023 12:42 |
| Letzte Änderung: | 02 Mai 2023 06:20 |
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| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
- Guest Ion‐Dependent Reaction Mechanisms of New Pseudocapacitive Mg₃V₄(PO₄)₆/Carbon Composite as Negative Electrode for Monovalent‐Ion Batteries. (deposited 28 Apr 2023 12:42) [Gegenwärtig angezeigt]
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