Hübner, Hanna ; Niebuur, Bart‐Jan ; Janka, Oliver ; Gemmer, Lea ; Koch, Marcus ; Kraus, Tobias ; Kickelbick, Guido ; Stühn, Bernd ; Gallei, Markus (2023)
Crystalline Carbosilane‐Based Block Copolymers: Synthesis by Anionic Polymerization and Morphology Evaluation in the Bulk State.
In: Macromolecular Chemistry and Physics, 2022, 224 (3)
doi: 10.26083/tuprints-00023743
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
Block copolymers (BCPs) in the bulk state are known to self‐assemble into different morphologies depending on their polymer segment ratio. For polymers with amorphous and crystalline BCP segments, the crystallization process can be influenced significantly by the corresponding bulk morphology. Herein, the synthesis of the amorphous‐crystalline BCP poly(dimethyl silacyclobutane)‐block‐poly(2vinyl pyridine), (PDMSB‐b‐P2VP), by living anionic polymerization is reported. Polymers with overall molar masses ranging from 17 400 g to 592 200 g mol⁻¹ and PDMSB contents of 4.8–83.9 vol% are synthesized and characterized by size‐exclusion chromatography and NMR spectroscopy. The bulk morphology of the obtained polymers is investigated by means of transmission electron microscopy and small angle X‐ray scattering, revealing a plethora of self‐assembled structures, providing confined and nonconfined conditions. Subsequently, the influence of the previously determined morphologies and their resulting confinement on the crystallinity and crystallization behavior of PDMSB is analyzed via differential scanning calorimetry and powder X‐ray diffraction. Here, fractionated crystallization and supercooling effects are observable as well as different diffraction patterns of the PDMSB crystallites for confined and nonconfined domains.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2023 |
| Autor(en): | Hübner, Hanna ; Niebuur, Bart‐Jan ; Janka, Oliver ; Gemmer, Lea ; Koch, Marcus ; Kraus, Tobias ; Kickelbick, Guido ; Stühn, Bernd ; Gallei, Markus |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Crystalline Carbosilane‐Based Block Copolymers: Synthesis by Anionic Polymerization and Morphology Evaluation in the Bulk State |
| Sprache: | Englisch |
| Publikationsjahr: | 2023 |
| Ort: | Darmstadt |
| Publikationsdatum der Erstveröffentlichung: | 2022 |
| Verlag: | Wiley-VCH |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Macromolecular Chemistry and Physics |
| Jahrgang/Volume einer Zeitschrift: | 224 |
| (Heft-)Nummer: | 3 |
| Kollation: | 10 Seiten |
| DOI: | 10.26083/tuprints-00023743 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/23743 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung DeepGreen |
| Kurzbeschreibung (Abstract): | Block copolymers (BCPs) in the bulk state are known to self‐assemble into different morphologies depending on their polymer segment ratio. For polymers with amorphous and crystalline BCP segments, the crystallization process can be influenced significantly by the corresponding bulk morphology. Herein, the synthesis of the amorphous‐crystalline BCP poly(dimethyl silacyclobutane)‐block‐poly(2vinyl pyridine), (PDMSB‐b‐P2VP), by living anionic polymerization is reported. Polymers with overall molar masses ranging from 17 400 g to 592 200 g mol⁻¹ and PDMSB contents of 4.8–83.9 vol% are synthesized and characterized by size‐exclusion chromatography and NMR spectroscopy. The bulk morphology of the obtained polymers is investigated by means of transmission electron microscopy and small angle X‐ray scattering, revealing a plethora of self‐assembled structures, providing confined and nonconfined conditions. Subsequently, the influence of the previously determined morphologies and their resulting confinement on the crystallinity and crystallization behavior of PDMSB is analyzed via differential scanning calorimetry and powder X‐ray diffraction. Here, fractionated crystallization and supercooling effects are observable as well as different diffraction patterns of the PDMSB crystallites for confined and nonconfined domains. |
| Freie Schlagworte: | anionic polymerization, confinement, crystallization, microphase separation, morphology |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-237436 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 530 Physik 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 05 Fachbereich Physik 05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM) |
| Hinterlegungsdatum: | 28 Apr 2023 12:38 |
| Letzte Änderung: | 03 Mai 2023 09:42 |
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- Crystalline Carbosilane‐Based Block Copolymers: Synthesis by Anionic Polymerization and Morphology Evaluation in the Bulk State. (deposited 28 Apr 2023 12:38) [Gegenwärtig angezeigt]
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