Frosch, Torsten ; Tarcea, Nicolae ; Schmitt, Michael ; Thiele, Hans ; Langenhorst, Falko ; Popp, Jürgen (2007)
UV Raman Imaging - A Promising Tool for Astrobiology: Comparative Raman Studies with Different Excitation Wavelengths on SNC Martian Meteorites.
In: Analytical Chemistry, 79 (3)
doi: 10.1021/ac0618977
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

The great capabilities of UV Raman imaging have been demonstrated on the three Martian meteorites:  Sayh al Uhaymir, Dar al Gani, and Zagami. Raman spectra without disturbing fluorescence and with high signal-to-noise-ratios and full of spectral features were derived. This result is of utmost importance for the development of powerful instruments for space missions. By point scanning the surfaces of the meteorite samples, it was possible for the first time to construct UV-Raman images out of the array of Raman spectra. Deep-UV Raman images are to the best of our knowledge presented for the first time. The images were used for a discussion of the chemical−mineralogical composition and texture of the meteorite surfaces. Comparative Raman studies applying visible and NIR Raman excitation wavelengths demonstrate a much better performance for UV Raman excitation. This comparative study of different Raman excitation wavelengths at the same sample spots was done by constructing a versatile, robust sample holder with a fixed micro-raster. The overall advantages of UV resonance Raman spectroscopy in terms of sensitivity and selectivity are demonstrated and discussed. Finally the application of this new technique for a UV Raman instrument for envisaged astrobiological focused space missions is suggested.

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