Groszewicz, Pedro Braga ; Breitzke, Hergen ; Jo, Wook ; Rödel, Jürgen ; Buntkowsky, Gerd (2022)
Local structure of the B-site in BNT-xBT investigated by 47,49Ti NMR: Effect of barium content.
In: Journal of Applied Physics, 2017, 121 (11)
doi: 10.26083/tuprints-00019735
Artikel, Zweitveröffentlichung, Verlagsversion
 | Es ist eine neuere Version dieses Eintrags verfügbar. |
Kurzbeschreibung (Abstract)
Towards a deeper understanding of the local structure of the B-site in (100-x)(Bi1/2Na1/2)TiO3-xBaTiO3 (BNT-xBT) with 0 ≤ x ≤ 15, solid-state nuclear magnetic resonance (NMR) spectra of the titanium isotopes 47Ti and 49Ti were investigated. The 47,49Ti NMR spectra of BNT-xBT indicate a disordered local structure for the B-site of these perovskites. The line-shape of the titanium NMR spectra of BNT-xBT samples is found to be independent on the barium content. This fact implies that the local structure of the B-site remains invariant with respect to the structural changes that result from the chemical modification with barium. The analysis of 47,49Ti NMR spectra supports the hypothesis that the main structural changes across the morphotropic phase boundary in these solid-solutions are constrained to the A-site and are related to the tilting of rigid oxygen octahedra.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2022 |
| Autor(en): | Groszewicz, Pedro Braga ; Breitzke, Hergen ; Jo, Wook ; Rödel, Jürgen ; Buntkowsky, Gerd |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Local structure of the B-site in BNT-xBT investigated by 47,49Ti NMR: Effect of barium content |
| Sprache: | Englisch |
| Publikationsjahr: | 2022 |
| Publikationsdatum der Erstveröffentlichung: | 2017 |
| Verlag: | AIP Publishing |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Journal of Applied Physics |
| Jahrgang/Volume einer Zeitschrift: | 121 |
| (Heft-)Nummer: | 11 |
| Kollation: | 6 Seiten |
| DOI: | 10.26083/tuprints-00019735 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/19735 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichungsservice |
| Kurzbeschreibung (Abstract): | Towards a deeper understanding of the local structure of the B-site in (100-x)(Bi1/2Na1/2)TiO3-xBaTiO3 (BNT-xBT) with 0 ≤ x ≤ 15, solid-state nuclear magnetic resonance (NMR) spectra of the titanium isotopes 47Ti and 49Ti were investigated. The 47,49Ti NMR spectra of BNT-xBT indicate a disordered local structure for the B-site of these perovskites. The line-shape of the titanium NMR spectra of BNT-xBT samples is found to be independent on the barium content. This fact implies that the local structure of the B-site remains invariant with respect to the structural changes that result from the chemical modification with barium. The analysis of 47,49Ti NMR spectra supports the hypothesis that the main structural changes across the morphotropic phase boundary in these solid-solutions are constrained to the A-site and are related to the tilting of rigid oxygen octahedra. |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-197356 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Physikalische Chemie |
| Hinterlegungsdatum: | 11 Jan 2022 14:45 |
| Letzte Änderung: | 03 Jul 2024 02:27 |
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- Local structure of the B-site in BNT-xBT investigated by 47,49Ti NMR: Effect of barium content. (deposited 11 Jan 2022 14:45) [Gegenwärtig angezeigt]
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