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The Effect of Co-Monomer Content on the Swelling/Shrinking and Mechanical Behaviour of Individually Adsorbed PNIPAM Microgel Particles

Burmistrova, Anna ; Richter, Marcel ; Eisele, Michael ; Üzüm, Cagri ; Klitzing, Regine von (2021)
The Effect of Co-Monomer Content on the Swelling/Shrinking and Mechanical Behaviour of Individually Adsorbed PNIPAM Microgel Particles.
In: Polymers, 2011, 3 (4)
doi: 10.26083/tuprints-00019053
Artikel, Zweitveröffentlichung, Verlagsversion

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Kurzbeschreibung (Abstract)

The swelling/deswelling behaviour of microgel particles in the bulk and at the surface was studied and correlated to their mechanical properties. We focused on two kinds of particles: pure PNIPAM and PNIPAM-co-AAc particles. It was shown that the two step volume phase transition found for PNIPAM-co-AAc particles in the bulk disappears after the adsorption at the surface and only a one step transition was identified. The transition temperature increased strongly with increasing the co-monomer content. The dependence of the Young’s modulus of the adsorbed microgel particles on the temperature and the co-monomer content was discussed. The investigations were performed via DLS and SFM.

Typ des Eintrags: Artikel
Erschienen: 2021
Autor(en): Burmistrova, Anna ; Richter, Marcel ; Eisele, Michael ; Üzüm, Cagri ; Klitzing, Regine von
Art des Eintrags: Zweitveröffentlichung
Titel: The Effect of Co-Monomer Content on the Swelling/Shrinking and Mechanical Behaviour of Individually Adsorbed PNIPAM Microgel Particles
Sprache: Englisch
Publikationsjahr: 2021
Publikationsdatum der Erstveröffentlichung: 2011
Verlag: MDPI
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Polymers
Jahrgang/Volume einer Zeitschrift: 3
(Heft-)Nummer: 4
DOI: 10.26083/tuprints-00019053
URL / URN: https://tuprints.ulb.tu-darmstadt.de/19053
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Herkunft: Zweitveröffentlichungsservice
Kurzbeschreibung (Abstract):

The swelling/deswelling behaviour of microgel particles in the bulk and at the surface was studied and correlated to their mechanical properties. We focused on two kinds of particles: pure PNIPAM and PNIPAM-co-AAc particles. It was shown that the two step volume phase transition found for PNIPAM-co-AAc particles in the bulk disappears after the adsorption at the surface and only a one step transition was identified. The transition temperature increased strongly with increasing the co-monomer content. The dependence of the Young’s modulus of the adsorbed microgel particles on the temperature and the co-monomer content was discussed. The investigations were performed via DLS and SFM.

Status: Verlagsversion
URN: urn:nbn:de:tuda-tuprints-190530
Sachgruppe der Dewey Dezimalklassifikatin (DDC): 500 Naturwissenschaften und Mathematik > 530 Physik
Fachbereich(e)/-gebiet(e): 05 Fachbereich Physik
05 Fachbereich Physik > Institut für Physik Kondensierter Materie (IPKM)
Hinterlegungsdatum: 03 Sep 2021 12:55
Letzte Änderung: 08 Sep 2021 10:32
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