Wang, Kaili ; Mera, Gabriela (2021)
Chemical design of onion-like carbon-silicon diimide polymer composites.
In: Experimental Results, 2
doi: 10.1017/exp.2021.13
Artikel, Bibliographie
Dies ist die neueste Version dieses Eintrags.
Kurzbeschreibung (Abstract)
Herein, we report the synthesis and characterization of a novel class of polymer composites based on onion-like carbons (OLCs)-silicon diimide by a salt-free polycondensation reaction. The pyridine-catalyzed polymerization reaction was carried out in the presence of various contents (0.1, 0.5, 1, and 2 wt%) of carboxyl-functionalized OLCs in argon atmosphere to provide composites with well-dispersed and covalently incorporated 0D nanocarbons throughout the 3D matrix of silicon diimide polymer. A strong dependency of the optical properties (UV absorbance and the photoluminescence spectra) on the content of functionalized OLCs incorporated within the polymer matrix was observed. The novel polymer composites are suitable precursors for the design of advanced and multifunctional 0D-nanocarbon–containing Si3N4-based ceramic nanocomposites.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2021 |
| Autor(en): | Wang, Kaili ; Mera, Gabriela |
| Art des Eintrags: | Bibliographie |
| Titel: | Chemical design of onion-like carbon-silicon diimide polymer composites |
| Sprache: | Englisch |
| Publikationsjahr: | 20 August 2021 |
| Verlag: | Cambridge University Press |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Experimental Results |
| Jahrgang/Volume einer Zeitschrift: | 2 |
| DOI: | 10.1017/exp.2021.13 |
| Zugehörige Links: | |
| Kurzbeschreibung (Abstract): | Herein, we report the synthesis and characterization of a novel class of polymer composites based on onion-like carbons (OLCs)-silicon diimide by a salt-free polycondensation reaction. The pyridine-catalyzed polymerization reaction was carried out in the presence of various contents (0.1, 0.5, 1, and 2 wt%) of carboxyl-functionalized OLCs in argon atmosphere to provide composites with well-dispersed and covalently incorporated 0D nanocarbons throughout the 3D matrix of silicon diimide polymer. A strong dependency of the optical properties (UV absorbance and the photoluminescence spectra) on the content of functionalized OLCs incorporated within the polymer matrix was observed. The novel polymer composites are suitable precursors for the design of advanced and multifunctional 0D-nanocarbon–containing Si3N4-based ceramic nanocomposites. |
| Freie Schlagworte: | 0D-nanocarbon, onion-like carbons, polymer-derived ceramic composites, silicon diimide, silicon nitride |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe |
| TU-Projekte: | DFG|IO83/2-1|Neuartige 0D-Nano |
| Hinterlegungsdatum: | 24 Aug 2021 07:05 |
| Letzte Änderung: | 03 Jul 2024 02:52 |
| PPN: | |
| Projekte: | German Research Foundation DFG, Grant Number IO 83/2-1 |
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| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
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Chemical design of onion-like carbon-silicon diimide polymer composites. (deposited 14 Dez 2022 13:38)
- Chemical design of onion-like carbon-silicon diimide polymer composites. (deposited 24 Aug 2021 07:05) [Gegenwärtig angezeigt]
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