Dieringer, Paul ; Marx, Falko ; Alobaid, Falah ; Ströhle, Jochen ; Epple, Bernd (2021)
Process Control Strategies in Chemical Looping
Gasification - A Novel Process for the Production of
Biofuels Allowing for Net Negative CO2 Emissions.
In: Applied Sciences, 2020, 10 (12)
doi: 10.26083/tuprints-00014068
Artikel, Zweitveröffentlichung, Verlagsversion
 | Es ist eine neuere Version dieses Eintrags verfügbar. |
Kurzbeschreibung (Abstract)
Chemical looping gasification (CLG) is a novel gasification technique, allowing for the production of a nitrogen-free high calorific synthesis gas from solid hydrocarbon feedstocks, without requiring a costly air separation unit. Initial advances to better understand the CLG technology were made during first studies in lab and bench scale units and through basic process simulations. Yet, tailored process control strategies are required for larger CLG units, which are not equipped with auxiliary heating. Here, it becomes a demanding task to achieve autothermal CLG operation, for which stable reactor temperatures are obtained. This study presents two avenues to attain autothermal CLG behavior, established through equilibrium based process simulations. As a first approach, the dilution of active oxygen carrier materials with inert heat carriers to limit oxygen transport to the fuel reactor has been investigated. Secondly, the suitability of restricting the air flow to the air reactor in order to control the oxygen availability in the fuel reactor was examined. Process simulations show that both process control approaches facilitate controlled and de-coupled heat and oxygen transport between the two reactors of the chemical looping gasifier, thus allowing for efficient autothermal CLG operation. With the aim of inferring general guidelines on how CLG units have to be operated in order to achieve decent synthesis gas yields, different advantages and disadvantages associated to the two suggested process control strategies are discussed in detail and optimization avenues are presented.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2021 |
| Autor(en): | Dieringer, Paul ; Marx, Falko ; Alobaid, Falah ; Ströhle, Jochen ; Epple, Bernd |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | Process Control Strategies in Chemical Looping Gasification - A Novel Process for the Production of Biofuels Allowing for Net Negative CO2 Emissions |
| Sprache: | Englisch |
| Publikationsjahr: | 2021 |
| Publikationsdatum der Erstveröffentlichung: | 2020 |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Applied Sciences |
| Jahrgang/Volume einer Zeitschrift: | 10 |
| (Heft-)Nummer: | 12 |
| Kollation: | 26 Seiten |
| DOI: | 10.26083/tuprints-00014068 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/14068 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung |
| Kurzbeschreibung (Abstract): | Chemical looping gasification (CLG) is a novel gasification technique, allowing for the production of a nitrogen-free high calorific synthesis gas from solid hydrocarbon feedstocks, without requiring a costly air separation unit. Initial advances to better understand the CLG technology were made during first studies in lab and bench scale units and through basic process simulations. Yet, tailored process control strategies are required for larger CLG units, which are not equipped with auxiliary heating. Here, it becomes a demanding task to achieve autothermal CLG operation, for which stable reactor temperatures are obtained. This study presents two avenues to attain autothermal CLG behavior, established through equilibrium based process simulations. As a first approach, the dilution of active oxygen carrier materials with inert heat carriers to limit oxygen transport to the fuel reactor has been investigated. Secondly, the suitability of restricting the air flow to the air reactor in order to control the oxygen availability in the fuel reactor was examined. Process simulations show that both process control approaches facilitate controlled and de-coupled heat and oxygen transport between the two reactors of the chemical looping gasifier, thus allowing for efficient autothermal CLG operation. With the aim of inferring general guidelines on how CLG units have to be operated in order to achieve decent synthesis gas yields, different advantages and disadvantages associated to the two suggested process control strategies are discussed in detail and optimization avenues are presented. |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-140684 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften und Maschinenbau |
| Fachbereich(e)/-gebiet(e): | 16 Fachbereich Maschinenbau 16 Fachbereich Maschinenbau > Institut für Energiesysteme und Energietechnik (EST) |
| Hinterlegungsdatum: | 30 Jun 2021 12:11 |
| Letzte Änderung: | 06 Jul 2021 05:32 |
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| Suche nach Titel in: | TUfind oder in Google |
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- Process Control Strategies in Chemical Looping Gasification - A Novel Process for the Production of Biofuels Allowing for Net Negative CO2 Emissions. (deposited 30 Jun 2021 12:11) [Gegenwärtig angezeigt]
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