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Nanomechanical characterisation of a water-repelling terpolymer coating of cellulosic fibres

Auernhammer, Julia ; Bell, Alena K. ; Schulze, Marcus ; Du, Yue ; Stühn, Lukas ; Wendenburg, Sonja ; Pause, Isabelle ; Biesalski, Markus ; Ensinger, Wolfgang ; Stark, Robert W. (2021)
Nanomechanical characterisation of a water-repelling terpolymer coating of cellulosic fibres.
In: Cellulose, 28 (4)
doi: 10.1007/s10570-020-03675-9
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

Polymer coatings on cellulosic fibres are widely used to enhance the natural fibre properties by improving, for example, the hydrophobicity and wet strength. Here, we investigate the effects of a terpolymer P(S-co-MABP-co-PyMA) coating on cotton linters and eucalyptus fibres to improve the resistance of cellulose fibres against wetness. Coated and uncoated fibres were characterised by using scanning electron microscopy, contact angle measurements, Raman spectroscopy and atomic force microscopy with the objective of correlating macroscopic properties such as the hydrophobicity of the fleece with microscopic properties such as the coating distribution and local nanomechanics. The scanning electron and fluorescence microscopy results revealed the distribution of the coating on the paper fleeces and fibres. Contact angle measurements proved the hydrophobic character of the coated fleece, which was also confirmed by Raman spectroscopy measurements that investigated the water uptake in single fibres. The water uptake also induced a change in the local mechanical properties, as measured by atomic force microscopy. These results verify the basic functionality of the hydrophobic coating on fibres and paper fleeces but call into question the homogeneity of the coating.

Typ des Eintrags: Artikel
Erschienen: 2021
Autor(en): Auernhammer, Julia ; Bell, Alena K. ; Schulze, Marcus ; Du, Yue ; Stühn, Lukas ; Wendenburg, Sonja ; Pause, Isabelle ; Biesalski, Markus ; Ensinger, Wolfgang ; Stark, Robert W.
Art des Eintrags: Bibliographie
Titel: Nanomechanical characterisation of a water-repelling terpolymer coating of cellulosic fibres
Sprache: Englisch
Publikationsjahr: 2021
Verlag: Springer Science
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Cellulose
Jahrgang/Volume einer Zeitschrift: 28
(Heft-)Nummer: 4
DOI: 10.1007/s10570-020-03675-9
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Kurzbeschreibung (Abstract):

Polymer coatings on cellulosic fibres are widely used to enhance the natural fibre properties by improving, for example, the hydrophobicity and wet strength. Here, we investigate the effects of a terpolymer P(S-co-MABP-co-PyMA) coating on cotton linters and eucalyptus fibres to improve the resistance of cellulose fibres against wetness. Coated and uncoated fibres were characterised by using scanning electron microscopy, contact angle measurements, Raman spectroscopy and atomic force microscopy with the objective of correlating macroscopic properties such as the hydrophobicity of the fleece with microscopic properties such as the coating distribution and local nanomechanics. The scanning electron and fluorescence microscopy results revealed the distribution of the coating on the paper fleeces and fibres. Contact angle measurements proved the hydrophobic character of the coated fleece, which was also confirmed by Raman spectroscopy measurements that investigated the water uptake in single fibres. The water uptake also induced a change in the local mechanical properties, as measured by atomic force microscopy. These results verify the basic functionality of the hydrophobic coating on fibres and paper fleeces but call into question the homogeneity of the coating.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Physics of Surfaces
07 Fachbereich Chemie
07 Fachbereich Chemie > Ernst-Berl-Institut
07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie
Hinterlegungsdatum: 15 Mär 2021 06:31
Letzte Änderung: 11 Dez 2024 07:41
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