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Larch-derived hierarchical nitrogen-doped carbon with echinus-like architecture for supercapacitor applications

Chen, Honglei ; Sha, Lei ; Zhang, Yujie ; Wang, Shoujuan ; Kong, Fangong ; Muench, Falk ; Zhao, Xin (2020)
Larch-derived hierarchical nitrogen-doped carbon with echinus-like architecture for supercapacitor applications.
In: Holzforschung, 74 (5)
doi: 10.1515/hf-2019-0074
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Echinus-like nitrogen-doped carbon with a hierarchical porous structure was synthesized from green larch waste and urea via liquid in situ doping and high-temperature carbonization. Benefitting from a large specific surface area (649 m(2) g(-1)) and hierarchical porous structure, the nitrogen-doped carbon exhibited excellent electrochemical performance for supercapacitors. Remarkably, the echinus-like nitrogen-doped carbon achieved a high specific capacitance of 340 F g(-1) at a current density of 1 A g(-1) in 6 M KOH electrolyte as well as a good performance rate and stability (with a capacitance retention of 98% after 5000 cycles). This capacitance was almost 1.5 times higher than that of undoped carbon due to the contribution of the pseudocapacitance from the nitrogen doping. Larch sawdust is a promising carbon source for fabricating inexpensive, sustainable and high-performance supercapacitor materials.

Typ des Eintrags: Artikel
Erschienen: 2020
Autor(en): Chen, Honglei ; Sha, Lei ; Zhang, Yujie ; Wang, Shoujuan ; Kong, Fangong ; Muench, Falk ; Zhao, Xin
Art des Eintrags: Bibliographie
Titel: Larch-derived hierarchical nitrogen-doped carbon with echinus-like architecture for supercapacitor applications
Sprache: Englisch
Publikationsjahr: Mai 2020
Verlag: De Gruyter
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Holzforschung
Jahrgang/Volume einer Zeitschrift: 74
(Heft-)Nummer: 5
DOI: 10.1515/hf-2019-0074
URL / URN: https://www.degruyter.com/view/journals/hfsg/74/5/article-p5...
Kurzbeschreibung (Abstract):

Echinus-like nitrogen-doped carbon with a hierarchical porous structure was synthesized from green larch waste and urea via liquid in situ doping and high-temperature carbonization. Benefitting from a large specific surface area (649 m(2) g(-1)) and hierarchical porous structure, the nitrogen-doped carbon exhibited excellent electrochemical performance for supercapacitors. Remarkably, the echinus-like nitrogen-doped carbon achieved a high specific capacitance of 340 F g(-1) at a current density of 1 A g(-1) in 6 M KOH electrolyte as well as a good performance rate and stability (with a capacitance retention of 98% after 5000 cycles). This capacitance was almost 1.5 times higher than that of undoped carbon due to the contribution of the pseudocapacitance from the nitrogen doping. Larch sawdust is a promising carbon source for fabricating inexpensive, sustainable and high-performance supercapacitor materials.

Freie Schlagworte: Echinus-like carbon, larch liquefaction, liquid in situ doping, supercapacitors
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik
Hinterlegungsdatum: 20 Nov 2020 08:13
Letzte Änderung: 20 Nov 2020 08:13
PPN:
Projekte: National Natural Science Foundation of China (NSFC), Grant number 31800499, 31600472, 31570566, Natural Science Foundation of Shandong Province, Grant number ZR2017LEM009, ZR2016YL007, Joint Research Fund for young doctor of Qilu University of Technology (Shandong Academy of Sciences), Grant number 2017BSH2010, Key Research and Development Program of Shandong Province, Grant number 2017GSF17130, Foundation of Guangxi Key Laboratory of Clean Pulp and Papermaking and Pollution Control of China, Grant number, KF201813-4, KF201717, Foundation of Key Laboratory of Pulp and Paper Science and Technology of the Ministry of Education/Shandong Province of China, Grant number ZR201707, ZR201710
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