Grätz, Sven ; Zink, Sebastian ; Kraffczyk, Hanna ; Rose, Marcus ; Borchardt, Lars (2019)
Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors.
In: Beilstein Journal of Organic Chemistry, 15
doi: 10.3762/bjoc.15.112
Artikel, Bibliographie
Dies ist die neueste Version dieses Eintrags.
Kurzbeschreibung (Abstract)
This study elucidates a mechanochemical polymerization reaction towards a hyper-crosslinked polymer as an alternative to conventional solvent-based procedures. The swift and solvent-free Friedel–Crafts alkylation reaction yields a porous polymer with surface areas of up to 1720 m2g −1 and pore volumes of up to 1.55 cm3g −1. The application of LAG (liquid-assisted grinding) revealed a profound impact of the liquid´s boiling point on the textural properties of the obtained polymer materials. Finally, the materials are characterized by vapour sorption experiments with benzene and cyclohexane.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2019 |
| Autor(en): | Grätz, Sven ; Zink, Sebastian ; Kraffczyk, Hanna ; Rose, Marcus ; Borchardt, Lars |
| Art des Eintrags: | Bibliographie |
| Titel: | Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors |
| Sprache: | Englisch |
| Publikationsjahr: | Mai 2019 |
| Ort: | Frankfurt am Main |
| Verlag: | Beilstein-Institut zur Förderung der Chemischen Wissenschaften |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Beilstein Journal of Organic Chemistry |
| Jahrgang/Volume einer Zeitschrift: | 15 |
| DOI: | 10.3762/bjoc.15.112 |
| Zugehörige Links: | |
| Kurzbeschreibung (Abstract): | This study elucidates a mechanochemical polymerization reaction towards a hyper-crosslinked polymer as an alternative to conventional solvent-based procedures. The swift and solvent-free Friedel–Crafts alkylation reaction yields a porous polymer with surface areas of up to 1720 m2g −1 and pore volumes of up to 1.55 cm3g −1. The application of LAG (liquid-assisted grinding) revealed a profound impact of the liquid´s boiling point on the textural properties of the obtained polymer materials. Finally, the materials are characterized by vapour sorption experiments with benzene and cyclohexane. |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie > Technische Chemie II |
| Hinterlegungsdatum: | 26 Nov 2019 06:50 |
| Letzte Änderung: | 19 Feb 2024 09:34 |
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| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
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Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors. (deposited 18 Nov 2021 10:47)
- Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors. (deposited 26 Nov 2019 06:50) [Gegenwärtig angezeigt]
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