Siebert, Jan Paul ; Bischoff, Lothar ; Lepple, Maren ; Zintler, Alexander ; Molina-Luna, Leopoldo ; Wiedwald, Ulf ; Birkel, Christina S. (2019)
Sol-gel based synthesis and enhanced processability of MAX phase Cr2GaC.
In: Journal of Materials Chemistry C, 7 (20)
doi: 10.1039/C9TC01416K
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
MAX phases are typically prepared by high-temperature (oftentimes high-pressure) solid-state methods. Here, we report a new wet chemistry based synthesis technique starting from an aqueous solution of metal nitrates and citric acid to prepare MAX phase Cr2GaC. This solution-processable precursor mixture has the potential to be easily scaled, painted, printed or fabricated onto supports-an advantage that is demonstrated by the formation of hollow carbon microspheres which are decorated with Cr2GaC particles. A small amount of chromium carbide and oxide remains in the product, however, the amount of the latter can be reduced by a larger excess in citric acid in the precursor gel. The transformation mechanism of the initial amorphous gel into highly crystalline and anisotropic MAX phase particles is investigated by detailed thermal analysis. Transmission electron microscopy studies are conducted to elucidate the microstructure of the sol-gel-prepared particles as well as the decorated hollow microspheres. From magnetic susceptibility measurements, the density of states at the Fermi level is deduced reflecting the quality of the Pauli paramagnet Cr2GaC.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2019 |
| Autor(en): | Siebert, Jan Paul ; Bischoff, Lothar ; Lepple, Maren ; Zintler, Alexander ; Molina-Luna, Leopoldo ; Wiedwald, Ulf ; Birkel, Christina S. |
| Art des Eintrags: | Bibliographie |
| Titel: | Sol-gel based synthesis and enhanced processability of MAX phase Cr2GaC |
| Sprache: | Englisch |
| Publikationsjahr: | 25 April 2019 |
| Verlag: | RSC Publishing |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Journal of Materials Chemistry C |
| Jahrgang/Volume einer Zeitschrift: | 7 |
| (Heft-)Nummer: | 20 |
| DOI: | 10.1039/C9TC01416K |
| Kurzbeschreibung (Abstract): | MAX phases are typically prepared by high-temperature (oftentimes high-pressure) solid-state methods. Here, we report a new wet chemistry based synthesis technique starting from an aqueous solution of metal nitrates and citric acid to prepare MAX phase Cr2GaC. This solution-processable precursor mixture has the potential to be easily scaled, painted, printed or fabricated onto supports-an advantage that is demonstrated by the formation of hollow carbon microspheres which are decorated with Cr2GaC particles. A small amount of chromium carbide and oxide remains in the product, however, the amount of the latter can be reduced by a larger excess in citric acid in the precursor gel. The transformation mechanism of the initial amorphous gel into highly crystalline and anisotropic MAX phase particles is investigated by detailed thermal analysis. Transmission electron microscopy studies are conducted to elucidate the microstructure of the sol-gel-prepared particles as well as the decorated hollow microspheres. From magnetic susceptibility measurements, the density of states at the Fermi level is deduced reflecting the quality of the Pauli paramagnet Cr2GaC. |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Elektronenmikroskopie 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Theorie magnetischer Materialien 07 Fachbereich Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie |
| Hinterlegungsdatum: | 20 Mai 2019 05:29 |
| Letzte Änderung: | 01 Feb 2023 07:35 |
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