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Tuning of electrocaloric performance in (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 by induced relaxor-like behavior

Weyland, Florian ; Hayati, Raziye ; Novak, Nikola (2019)
Tuning of electrocaloric performance in (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 by induced relaxor-like behavior.
In: Ceramics international, 2019 (45)
doi: 10.1016/j.ceramint.2019.03.006
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Induced relaxor-like behavior is reported by addition of a sintering additive to the (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 solid solution. The effect of Bi2O3 sinter additive on microstructure is determined. The phase transition behavioris highlighted by dielectric permittivity measurements. The electrocaloric temperature change is directly measured and comparison with literature data is provided on basis of the material related cooling power. Addition of Bi2O3 drastically increases the temperature stability and an ultra-wide temperature range of over 100 K is achieved. The findings path a way to tune electrocaloric materials for optimization of properties for solid-state coolers based on the electrocaloric effect.

Typ des Eintrags: Artikel
Erschienen: 2019
Autor(en): Weyland, Florian ; Hayati, Raziye ; Novak, Nikola
Art des Eintrags: Bibliographie
Titel: Tuning of electrocaloric performance in (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 by induced relaxor-like behavior
Sprache: Englisch
Publikationsjahr: 23 April 2019
Verlag: Elsevier SCI LTD, Oxford, England
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Ceramics international
Jahrgang/Volume einer Zeitschrift: 2019
(Heft-)Nummer: 45
DOI: 10.1016/j.ceramint.2019.03.006
Kurzbeschreibung (Abstract):

Induced relaxor-like behavior is reported by addition of a sintering additive to the (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 solid solution. The effect of Bi2O3 sinter additive on microstructure is determined. The phase transition behavioris highlighted by dielectric permittivity measurements. The electrocaloric temperature change is directly measured and comparison with literature data is provided on basis of the material related cooling power. Addition of Bi2O3 drastically increases the temperature stability and an ultra-wide temperature range of over 100 K is achieved. The findings path a way to tune electrocaloric materials for optimization of properties for solid-state coolers based on the electrocaloric effect.

Freie Schlagworte: Electrical properties Ferroelectric properties BaTiO3 and titanates Perovskites
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
Hinterlegungsdatum: 23 Apr 2019 10:46
Letzte Änderung: 23 Apr 2019 10:46
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