Rüttiger, Christian ; Vowinkel, Steffen ; Herzog, Nicole ; Hofmann, Kathrin ; Ionescu, Emanuel ; Gallei, Markus (2019)
POSS-Containing Polymethacrylates on Cellulose-Based Substrates: Immobilization and Ceramic Formation.
In: Coatings, 2018, 8 (12)
doi: 10.3390/coatings8120446
Artikel, Zweitveröffentlichung, Verlagsversion
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Kurzbeschreibung (Abstract)
The combination of cellulose-based materials and functional polymers is a promising approach for the preparation of porous, biotemplated ceramic materials. Within this study, cellulose substrates were functionalized with a surface-attached initiator followed by polymerization of (3-methacryloxypropyl)heptaisobutyl-T8-silsesquioxane (MAPOSS) by means of surface-initiated atom transfer radical polymerization (ATRP). Successful functionalization was proven by infrared (IR) spectroscopy as well as by contact angle (CA) measurements. Thermal analysis of the polymer-modified cellulose substrates in different atmospheres (nitrogen and air) up to 600 ◦C led to porous carbon materials featuring the pristine fibre-like structure of the cellulose material as shown by scanning electron microscopy (SEM). Interestingly, spherical, silicon-containing domains were present at the surface of the cellulose-templated carbon fibres after further ceramisation at 1600 ◦C, as investigated by energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) measurements.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2019 |
| Autor(en): | Rüttiger, Christian ; Vowinkel, Steffen ; Herzog, Nicole ; Hofmann, Kathrin ; Ionescu, Emanuel ; Gallei, Markus |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | POSS-Containing Polymethacrylates on Cellulose-Based Substrates: Immobilization and Ceramic Formation |
| Sprache: | Englisch |
| Publikationsjahr: | 2019 |
| Publikationsdatum der Erstveröffentlichung: | 2018 |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Coatings |
| Jahrgang/Volume einer Zeitschrift: | 8 |
| (Heft-)Nummer: | 12 |
| DOI: | 10.3390/coatings8120446 |
| URL / URN: | https://doi.org/10.3390/coatings8120446 |
| Herkunft: | Zweitveröffentlichung aus gefördertem Golden Open Access |
| Kurzbeschreibung (Abstract): | The combination of cellulose-based materials and functional polymers is a promising approach for the preparation of porous, biotemplated ceramic materials. Within this study, cellulose substrates were functionalized with a surface-attached initiator followed by polymerization of (3-methacryloxypropyl)heptaisobutyl-T8-silsesquioxane (MAPOSS) by means of surface-initiated atom transfer radical polymerization (ATRP). Successful functionalization was proven by infrared (IR) spectroscopy as well as by contact angle (CA) measurements. Thermal analysis of the polymer-modified cellulose substrates in different atmospheres (nitrogen and air) up to 600 ◦C led to porous carbon materials featuring the pristine fibre-like structure of the cellulose material as shown by scanning electron microscopy (SEM). Interestingly, spherical, silicon-containing domains were present at the surface of the cellulose-templated carbon fibres after further ceramisation at 1600 ◦C, as investigated by energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) measurements. |
| Freie Schlagworte: | immobilized polymers; controlled polymerizations; ceramic precursors; cellulose; ATRP POLYMER-DERIVED CERAMICS; MELT-SHEAR ORGANIZATION; RADICAL POLYMERIZATION; PAPER; SURFACE; NANOPARTICLES; ATRP; NANOSTRUCTURES; NANOCOMPOSITES; NANOCRYSTALS |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-85037 |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe 07 Fachbereich Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut 07 Fachbereich Chemie > Eduard Zintl-Institut 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Physikalische Chemie |
| Hinterlegungsdatum: | 24 Feb 2019 20:55 |
| Letzte Änderung: | 02 Jul 2024 23:05 |
| PPN: | |
| Sponsoren: | German Research Foundation DFG: GA2169/7-1, DFG-PAK 962/1 |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
Verfügbare Versionen dieses Eintrags
- POSS-Containing Polymethacrylates on Cellulose-Based Substrates: Immobilization and Ceramic Formation. (deposited 24 Feb 2019 20:55) [Gegenwärtig angezeigt]
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