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Gallium/Indium-based nitrides and oxynitrides derived from organometallic precursors

Kinski, Isabel ; Maurer, Florian ; Riedel, Ralf (2004)
Gallium/Indium-based nitrides and oxynitrides derived from organometallic precursors.
4th International Symposium on Nitrides. Mons, BELGIUM (17.11.2003-19.11.2003)
Konferenzveröffentlichung, Bibliographie

Kurzbeschreibung (Abstract)

Bulk phases of pure GaN, pure InN and solid solutions of compositions InxGa1-xN have been synthesized by pyrolysis of organometallic precursors via ammonolysis. The prior molecular structure of the precursors leads to a good distribution of Ga and In on cation sites in the solid solutions. In GaN and InN with the wurtzite structure, solid solutions follow Vegard's law and therefore the lattice constant a(0) gives information about the degree of cation substitution in the structure. XRD and microscopic methods (SEM and TEM coupled with EDX) were used to investigate synthesized bulk phases. We report here on organometallic precursors suitable for the synthesis of group 13 nitrides. Modification of the precursors with oxygen-containing substances provides appropriate molecules that can be transformed via ammonolysis to oxynitrides.

Typ des Eintrags: Konferenzveröffentlichung
Erschienen: 2004
Autor(en): Kinski, Isabel ; Maurer, Florian ; Riedel, Ralf
Art des Eintrags: Bibliographie
Titel: Gallium/Indium-based nitrides and oxynitrides derived from organometallic precursors
Sprache: Englisch
Publikationsjahr: Mai 2004
Verlag: BELGIAN CERAMIC SOCIETY, 4 AVE GOUVERNEUR CORNEZ, B-7000 MONS, BELGIUM
Buchtitel: SILICATES INDUSTRIELS
Reihe: 69
Band einer Reihe: 5-6 Special Issue 1
Veranstaltungstitel: 4th International Symposium on Nitrides
Veranstaltungsort: Mons, BELGIUM
Veranstaltungsdatum: 17.11.2003-19.11.2003
Kurzbeschreibung (Abstract):

Bulk phases of pure GaN, pure InN and solid solutions of compositions InxGa1-xN have been synthesized by pyrolysis of organometallic precursors via ammonolysis. The prior molecular structure of the precursors leads to a good distribution of Ga and In on cation sites in the solid solutions. In GaN and InN with the wurtzite structure, solid solutions follow Vegard's law and therefore the lattice constant a(0) gives information about the degree of cation substitution in the structure. XRD and microscopic methods (SEM and TEM coupled with EDX) were used to investigate synthesized bulk phases. We report here on organometallic precursors suitable for the synthesis of group 13 nitrides. Modification of the precursors with oxygen-containing substances provides appropriate molecules that can be transformed via ammonolysis to oxynitrides.

Freie Schlagworte: gallium nitride, indium nitride, solid solution, precursor synthesis
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe
Hinterlegungsdatum: 17 Dez 2018 16:15
Letzte Änderung: 17 Dez 2018 16:15
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