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Imide-containing ladder polyphenylsilsesquioxanes with high thermal stability and thermoplastic properties

Chavez, Ricardo ; Ionescu, Emanuel ; Fasel, Claudia ; Riedel, Ralf (2013)
Imide-containing ladder polyphenylsilsesquioxanes with high thermal stability and thermoplastic properties.
In: Journal of Applied Polymer Science, 131 (7)
doi: 10.1002/app.40085
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

This work reports for the first time the synthesis of ladder polyphenylsilsesquioxanes containing imide building blocks as parts of the main parallel chains. The ladder structure of the synthesized polymers was documented by means of small angle X‐ray scattering (SAXS) measurements. The obtained ladder polymers exhibit stability with respect to decomposition up to temperatures as high as 460°C; additionally, they have melting points far below their decomposition temperatures, which make them interesting candidate materials for thermoplastic processing. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40085.

Typ des Eintrags: Artikel
Erschienen: 2013
Autor(en): Chavez, Ricardo ; Ionescu, Emanuel ; Fasel, Claudia ; Riedel, Ralf
Art des Eintrags: Bibliographie
Titel: Imide-containing ladder polyphenylsilsesquioxanes with high thermal stability and thermoplastic properties
Sprache: Englisch
Publikationsjahr: 5 April 2013
Verlag: Wiley-VCH Verlag GmbH, Weinheim
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of Applied Polymer Science
Jahrgang/Volume einer Zeitschrift: 131
(Heft-)Nummer: 7
DOI: 10.1002/app.40085
URL / URN: https://doi.org/10.1002/app.40085
Kurzbeschreibung (Abstract):

This work reports for the first time the synthesis of ladder polyphenylsilsesquioxanes containing imide building blocks as parts of the main parallel chains. The ladder structure of the synthesized polymers was documented by means of small angle X‐ray scattering (SAXS) measurements. The obtained ladder polymers exhibit stability with respect to decomposition up to temperatures as high as 460°C; additionally, they have melting points far below their decomposition temperatures, which make them interesting candidate materials for thermoplastic processing. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40085.

Freie Schlagworte: polyimides, thermoplastics, inorganic polymers, thermal properties
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe
Hinterlegungsdatum: 17 Dez 2018 13:32
Letzte Änderung: 17 Dez 2018 13:32
PPN:
Sponsoren: R.R. thanks the Fonds der Chemische Industrie for continuous financial support.
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