Gao, Zhonghui ; Hao, Zhangxiang ; Yi, Min ; Huang, Ying ; Xu, Yiming ; Zhao, Ying ; Li, Zhaoyang ; Zhu, Shengli ; Xu, Bai-Xiang ; Liu, Porun ; Wang, Feng Ryan ; Huang, Yunhui ; Zhao, Huijun ; Yang, Xianjin (2018)
Correlation between Mechanical Strength of Amorphous TiO2 Nanotubes and Their Solid State Crystallization Pathways.
In: Chemistry Select, 3 (38)
doi: 10.1002/slct.201802588
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
Developing TiO2 crystals with specific morphologies and nanostructured architectures is highly desirable in energy storage, conversion and catalysis applications. Thermally activated amorphous‐to‐crystal transition provides effective growth of poly or monocrystalline TiO2, while an in‐depth understanding of different crystallization pathways at the solid state is still lacking. Herein, we report a close correlation between mechanical strength of the TiO2 precursors and their different crystallization pathways. Two different morphologies, i. e., well‐defined anatase TiO2 single nanocrystals and anatase polycrystalline nanotubes are obtained via rapid heating of two amorphous TiO2 precursors with distinctive mechanical strengths. The mechanical‐strength‐dependent crystallization from amorphous solid‐state precursors provides additional control on the crystallization pathway and thus the desirable properties of the resultant nanostructures. In this study, the well‐defined anatase nanocrystals with controlled morphology show higher storage capacity of sodium ion than that of polycrystalline ones in sodium ion batteries.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2018 |
| Autor(en): | Gao, Zhonghui ; Hao, Zhangxiang ; Yi, Min ; Huang, Ying ; Xu, Yiming ; Zhao, Ying ; Li, Zhaoyang ; Zhu, Shengli ; Xu, Bai-Xiang ; Liu, Porun ; Wang, Feng Ryan ; Huang, Yunhui ; Zhao, Huijun ; Yang, Xianjin |
| Art des Eintrags: | Bibliographie |
| Titel: | Correlation between Mechanical Strength of Amorphous TiO2 Nanotubes and Their Solid State Crystallization Pathways |
| Sprache: | Englisch |
| Publikationsjahr: | 16 Oktober 2018 |
| Verlag: | Wiley |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Chemistry Select |
| Jahrgang/Volume einer Zeitschrift: | 3 |
| (Heft-)Nummer: | 38 |
| DOI: | 10.1002/slct.201802588 |
| Kurzbeschreibung (Abstract): | Developing TiO2 crystals with specific morphologies and nanostructured architectures is highly desirable in energy storage, conversion and catalysis applications. Thermally activated amorphous‐to‐crystal transition provides effective growth of poly or monocrystalline TiO2, while an in‐depth understanding of different crystallization pathways at the solid state is still lacking. Herein, we report a close correlation between mechanical strength of the TiO2 precursors and their different crystallization pathways. Two different morphologies, i. e., well‐defined anatase TiO2 single nanocrystals and anatase polycrystalline nanotubes are obtained via rapid heating of two amorphous TiO2 precursors with distinctive mechanical strengths. The mechanical‐strength‐dependent crystallization from amorphous solid‐state precursors provides additional control on the crystallization pathway and thus the desirable properties of the resultant nanostructures. In this study, the well‐defined anatase nanocrystals with controlled morphology show higher storage capacity of sodium ion than that of polycrystalline ones in sodium ion batteries. |
| Freie Schlagworte: | Mechanical strength, Na-ion battery, Nanoindentation, TiO2 nanotubes |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Mechanik Funktionaler Materialien |
| Hinterlegungsdatum: | 26 Nov 2018 06:07 |
| Letzte Änderung: | 26 Jan 2024 09:21 |
| PPN: | |
| Sponsoren: | This work was financially supported by the China Postdoctoral Fund (0500229044), National Natural Science Foundation of China (51771131), the EPSRC First Grant project (EP/P02467X/1) and Royal Society research grant (RG160661). |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
 |
Frage zum Eintrag |
Optionen (nur für Redakteure)
 |
Redaktionelle Details anzeigen |
Drucken
Impressum