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The analysis of chemical time scales in a partial oxidation flame

Prüfert, U. ; Hunger, F. ; Hasse, C. (2014)
The analysis of chemical time scales in a partial oxidation flame.
In: Combustion and Flame, 161
doi: 10.1016/j.combustflame.2013.09.001
Article, Bibliographie

Abstract

Abstract Time scale analysis is a well-established method in combustion science to identify slow and fast processes, but is also required for multi-scale modeling of turbulence-chemistry interaction. Models such as flamelet are based on scale separation arguments, which require a suitable definition of chemical time scales. In this article we study different time scale definitions. Two definitions previously published in the literature as well as two new definitions are investigated in detail. Most time scales require the computation of the eigenvalues of the chemical Jacobian, which is computationally expensive especially for larger chemical reaction mechanisms. One of the new definitions also requires the Jacobian of the chemical source term, whereas the computation of the second newly proposed time scale is computationally straight-forward since neither one is needed. We evaluate the four methods on a simple one-step reacting system and a partial oxidation flame which combines an oxy-fuel type reaction and a fuel-rich reforming post flame zone. Most of the considered time scale definitions provide similar results whereas the computational effort differs significantly.

Item Type: Article
Erschienen: 2014
Creators: Prüfert, U. ; Hunger, F. ; Hasse, C.
Type of entry: Bibliographie
Title: The analysis of chemical time scales in a partial oxidation flame
Language: English
Date: 2014
Journal or Publication Title: Combustion and Flame
Volume of the journal: 161
DOI: 10.1016/j.combustflame.2013.09.001
URL / URN: http://dx.doi.org/10.1016/j.combustflame.2013.09.001
Corresponding Links:
Abstract:

Abstract Time scale analysis is a well-established method in combustion science to identify slow and fast processes, but is also required for multi-scale modeling of turbulence-chemistry interaction. Models such as flamelet are based on scale separation arguments, which require a suitable definition of chemical time scales. In this article we study different time scale definitions. Two definitions previously published in the literature as well as two new definitions are investigated in detail. Most time scales require the computation of the eigenvalues of the chemical Jacobian, which is computationally expensive especially for larger chemical reaction mechanisms. One of the new definitions also requires the Jacobian of the chemical source term, whereas the computation of the second newly proposed time scale is computationally straight-forward since neither one is needed. We evaluate the four methods on a simple one-step reacting system and a partial oxidation flame which combines an oxy-fuel type reaction and a fuel-rich reforming post flame zone. Most of the considered time scale definitions provide similar results whereas the computational effort differs significantly.

Divisions: 16 Department of Mechanical Engineering > Simulation of reactive Thermo-Fluid Systems (STFS)
16 Department of Mechanical Engineering
Date Deposited: 29 Nov 2017 14:59
Last Modified: 29 Nov 2017 14:59
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