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Synthesis, characterization, molecular structure and supramolecular architectures of some copper(II) complexes derived from salicylaldehyde semicarbazone

Salem, Nahed M. H. ; Rashad, Amal R. ; El Sayed, Laila ; Foro, Sabine ; Haase, Wolfgang ; Iskander, Magdi F. (2015):
Synthesis, characterization, molecular structure and supramolecular architectures of some copper(II) complexes derived from salicylaldehyde semicarbazone.
In: Inorganica Chimica Acta, 432, pp. 231-242. ELSEVIER SCIENCE SA, Switzerland, ISSN 00201693,
[Article]

Abstract

A series of new copper(II) complexes, [Cu(HSalsc)Cl]center dot 1/2H(2)O (1), [{Cu(HSalsc)}(2)(NO3)(2)][{Cu(HSalsc)}(2)- NO3)center dot H2O]NO3 (2), [{Cu(Salsc)}(2)]H2O (3), [Cu(HSalsc)(HIm)]Cl center dot 1/2H(2)O (4), [{Cu(HSalsc)HIm}(2)](NO3)(2) (5) and [Cu(HSalsc)(HIm)]OAc (6) derived from salicylaldehyde semicarbazone (H(2)Salsc) have been prepared and characterized by elemental analysis, infrared and UV-Vis absorption spectra as well as electrospray mass spectra (ESI-MS). The crystal and molecular structure of 1, 2, 5 and 6 have been determined by X-ray single crystal diffraction. The supramolecular architectures in 1, 2, 5 and 6 have been also discussed. (C) 2015 Elsevier B.V. All rights reserved.

Item Type: Article
Erschienen: 2015
Creators: Salem, Nahed M. H. ; Rashad, Amal R. ; El Sayed, Laila ; Foro, Sabine ; Haase, Wolfgang ; Iskander, Magdi F.
Title: Synthesis, characterization, molecular structure and supramolecular architectures of some copper(II) complexes derived from salicylaldehyde semicarbazone
Language: English
Abstract:

A series of new copper(II) complexes, [Cu(HSalsc)Cl]center dot 1/2H(2)O (1), [{Cu(HSalsc)}(2)(NO3)(2)][{Cu(HSalsc)}(2)- NO3)center dot H2O]NO3 (2), [{Cu(Salsc)}(2)]H2O (3), [Cu(HSalsc)(HIm)]Cl center dot 1/2H(2)O (4), [{Cu(HSalsc)HIm}(2)](NO3)(2) (5) and [Cu(HSalsc)(HIm)]OAc (6) derived from salicylaldehyde semicarbazone (H(2)Salsc) have been prepared and characterized by elemental analysis, infrared and UV-Vis absorption spectra as well as electrospray mass spectra (ESI-MS). The crystal and molecular structure of 1, 2, 5 and 6 have been determined by X-ray single crystal diffraction. The supramolecular architectures in 1, 2, 5 and 6 have been also discussed. (C) 2015 Elsevier B.V. All rights reserved.

Journal or Publication Title: Inorganica Chimica Acta
Journal volume: 432
Publisher: ELSEVIER SCIENCE SA, Switzerland
Uncontrolled Keywords: Salicylaldehyde semicarbazone Cu(II) complexes, Synthesis, Characterization, X-ray crystal structures, Supramolecular architectures
Divisions: 11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences > Material Science > Structure Research
07 Department of Chemistry
11 Department of Materials and Earth Sciences
Date Deposited: 19 Jan 2016 12:50
Official URL: http://dx.doi.org/10.1016/j.ica.2015.04.019
Identification Number: doi:10.1016/j.ica.2015.04.019
Funders: Thanks are due to DFG (1.8131e-2/09) for supporting this bilateral project.
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