Renard, Laetitia ; Brötz, Joachim ; Fuess, Hartmut ; Gurlo, Aleksander ; Riedel, Ralf ; Toupance, Thierry (2014)
Hybrid Organotin and Tin Oxide-based Thin Films Processed from Alkynylorganotins: Synthesis, Characterization, and Gas Sensing Properties.
In: ACS Applied Materials & Interfaces, 6 (19)
Article
Abstract
Hydrolysis–condensation of bis(triprop-1-ynylstannyl)butylene led to nanostructured bridged polystannoxane films yielding tin dioxide thin layers upon UV-treatment or annealing in air. According to Fourier transform infrared (FTIR) spectroscopy, contact angle measurements, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning electron microscopy (SEM) data, the films were composed of a network of aggregated “pseudo-particles”, as calcination at 600 °C is required to form cassiterite nanocrystalline SnO2 particles. In the presence of reductive gases such as H2 and CO, these films gave rise to highly sensitive, reversible, and reproducible responses. The best selectivity toward H2 was reached at 150 °C with the hybrid thin films that do not show any response to CO at 20–200 °C. On the other hand, the SnO2 films prepared at 600 °C are more sensitive to H2 than to CO with best operating temperature in the 300–350 °C range. This organometallic approach provides an entirely new class of gas-sensing materials based on a class II organic–inorganic hybrid layer, along with a new way to include organic functionality in gas sensing metal oxides.
| Item Type: | Article |
|---|---|
| Erschienen: | 2014 |
| Creators: | Renard, Laetitia ; Brötz, Joachim ; Fuess, Hartmut ; Gurlo, Aleksander ; Riedel, Ralf ; Toupance, Thierry |
| Type of entry: | Bibliographie |
| Title: | Hybrid Organotin and Tin Oxide-based Thin Films Processed from Alkynylorganotins: Synthesis, Characterization, and Gas Sensing Properties. |
| Language: | English |
| Date: | 8 October 2014 |
| Publisher: | ACS Publications |
| Journal or Publication Title: | ACS Applied Materials & Interfaces |
| Volume of the journal: | 6 |
| Issue Number: | 19 |
| URL / URN: | http://dx.doi.org/10.1021/am504723t |
| Abstract: | Hydrolysis–condensation of bis(triprop-1-ynylstannyl)butylene led to nanostructured bridged polystannoxane films yielding tin dioxide thin layers upon UV-treatment or annealing in air. According to Fourier transform infrared (FTIR) spectroscopy, contact angle measurements, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning electron microscopy (SEM) data, the films were composed of a network of aggregated “pseudo-particles”, as calcination at 600 °C is required to form cassiterite nanocrystalline SnO2 particles. In the presence of reductive gases such as H2 and CO, these films gave rise to highly sensitive, reversible, and reproducible responses. The best selectivity toward H2 was reached at 150 °C with the hybrid thin films that do not show any response to CO at 20–200 °C. On the other hand, the SnO2 films prepared at 600 °C are more sensitive to H2 than to CO with best operating temperature in the 300–350 °C range. This organometallic approach provides an entirely new class of gas-sensing materials based on a class II organic–inorganic hybrid layer, along with a new way to include organic functionality in gas sensing metal oxides. |
| Uncontrolled Keywords: | organotins, organic−inorganic hybrid materials, tin dioxide, thin films, gas sensors |
| Identification Number: | doi:10.1021/am504723t |
| Divisions: | 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids 11 Department of Materials and Earth Sciences > Material Science > Structure Research 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences |
| Date Deposited: | 18 Nov 2014 08:30 |
| Last Modified: | 18 Nov 2014 08:30 |
| PPN: | |
| Funders: | This work was supported by the MENRT (LR fellowship), the CNRS, the Aquitaine Region (Contract no. 09002556) and the European Community (FAME Network of Excellence)., It was carried out within the framework of EMMI (European Multifunctional Material Institute). |
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