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Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films

Scheid, D. ; Lederle, C. ; Vowinkel, S. ; Schäfer, C. G. ; Stühn, B. ; Gallei, M. (2014)
Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films.
In: J. Mater. Chem. C, 2
Article, Bibliographie

Abstract

A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed.

Item Type: Article
Erschienen: 2014
Creators: Scheid, D. ; Lederle, C. ; Vowinkel, S. ; Schäfer, C. G. ; Stühn, B. ; Gallei, M.
Type of entry: Bibliographie
Title: Redox- and mechano-chromic response of metallopolymer-based elastomeric colloidal crystal films
Language: German
Date: 2014
Publisher: The Royal Society of Chemistry
Journal or Publication Title: J. Mater. Chem. C
Volume of the journal: 2
URL / URN: http://dx.doi.org/10.1039/C3TC32525C
Abstract:

A novel and convenient route for the preparation of monodisperse ferrocene-containing core-interlayer-shell particles using emulsion polymerisation protocols is described. These metallopolymer-based particles can be used to produce highly ordered elastomeric opal films with fascinating distinct reflection colours. The present work additionally describes the combined addressability of both stimuli, redox-chemistry and mechanical stress. The obtained materials are interesting since application of the melt-shear process followed by crosslinking of the matrix provides access to large-area, mechano-responsive elastomeric opal films featuring an additional redox response. Both, basic synthesis aspects and first steps towards application in the field of stimuli-responsive sensing of respective materials are discussed.

Divisions: 05 Department of Physics
05 Department of Physics > Institute for condensed matter physics (2021 merged in Institute for Condensed Matter Physics)
05 Department of Physics > Institute for condensed matter physics (2021 merged in Institute for Condensed Matter Physics) > Experimental Condensed Matter Physics
Date Deposited: 29 Jul 2014 12:59
Last Modified: 26 Aug 2018 21:28
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