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High-pressure free-radical copolymerization of ethene and butyl acrylate

Buback, M. and Busch, Markus and Lovis, K. and Mähling, F.-O. (1996):
High-pressure free-radical copolymerization of ethene and butyl acrylate.
In: Macromolecular Chemistry and Physics, 197 (1), pp. 303-313. Hüthig & Wepf Verlag, [Article]

Abstract

The free-radical copolymerization of ethene and butyl acrylate was studied between 130 and 225°C at pressures from 1 500 to 2 500 bar. The reactions which were induced either thermally or laser-photochemically were run in two types of continuously operated devices. Reactivity ratio data referring to ethene-rich monomer mixtures are presented. These data allow to estimate the copolymer composition in ethene/butyl acrylate copolymerizations carried out in a wide range of temperatures and pressures.

Item Type: Article
Erschienen: 1996
Creators: Buback, M. and Busch, Markus and Lovis, K. and Mähling, F.-O.
Title: High-pressure free-radical copolymerization of ethene and butyl acrylate
Language: English
Abstract:

The free-radical copolymerization of ethene and butyl acrylate was studied between 130 and 225°C at pressures from 1 500 to 2 500 bar. The reactions which were induced either thermally or laser-photochemically were run in two types of continuously operated devices. Reactivity ratio data referring to ethene-rich monomer mixtures are presented. These data allow to estimate the copolymer composition in ethene/butyl acrylate copolymerizations carried out in a wide range of temperatures and pressures.

Journal or Publication Title: Macromolecular Chemistry and Physics
Journal volume: 197
Number: 1
Publisher: Hüthig & Wepf Verlag
Divisions: 07 Department of Chemistry > Fachgebiet Technische Chemie > Technische Chemie III
07 Department of Chemistry > Fachgebiet Technische Chemie
07 Department of Chemistry
Date Deposited: 12 Dec 2012 11:07
Official URL: http://dx.doi.org/10.1002/macp.1996.021970123
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