Dittmer, Robert ; Anton, Eva-Maria ; Jo, Wook ; Simons, Hugh ; Daniels, John E. ; Hoffman, Mark ; Pokorny, Jan ; Reaney, Ian M. ; Rödel, Jürgen (2012)
A High-Temperature-Capacitor Dielectric Based on K0.5Na0.5NbO3-Modified Bi1/2Na1/2TiO3-Bi1/2K1/2TiO3.
In: Journal of the American Ceramic Society, 95 (11)
doi: 10.1111/j.1551-2916.2012.05321.x
Article, Bibliographie
Abstract
A high-temperature dielectric, (1–x)(0.6Bi1/2Na1/2TiO3–0.4Bi1/2K1/2TiO3)–xK0.5Na0.5NbO3, off the morphotropic phase boundary of the parent matrix 0.8Bi1/2Na1/2TiO3–0.2Bi1/2K1/2TiO3, has been developed for application as a high-temperature capacitor. In addition to temperature-dependent permittivity and dielectric loss, DC conductivity and field-dependent permittivity are reported. These properties are correlated with temperature-dependent structure data measured at different length scales using Raman spectroscopy and neutron diffraction. It is suggested that all materials investigated are ergodic relaxors with two types of polar nanoregions providing different relaxation mechanisms. The most attractive properties for application as high-temperature dielectrics are obtained in a material with x = 0.15 at less than 10% variation of relative permittivity of about 2100 between 54°C and 400°C.
| Item Type: | Article |
|---|---|
| Erschienen: | 2012 |
| Creators: | Dittmer, Robert ; Anton, Eva-Maria ; Jo, Wook ; Simons, Hugh ; Daniels, John E. ; Hoffman, Mark ; Pokorny, Jan ; Reaney, Ian M. ; Rödel, Jürgen |
| Type of entry: | Bibliographie |
| Title: | A High-Temperature-Capacitor Dielectric Based on K0.5Na0.5NbO3-Modified Bi1/2Na1/2TiO3-Bi1/2K1/2TiO3 |
| Language: | English |
| Date: | November 2012 |
| Journal or Publication Title: | Journal of the American Ceramic Society |
| Volume of the journal: | 95 |
| Issue Number: | 11 |
| DOI: | 10.1111/j.1551-2916.2012.05321.x |
| Abstract: | A high-temperature dielectric, (1–x)(0.6Bi1/2Na1/2TiO3–0.4Bi1/2K1/2TiO3)–xK0.5Na0.5NbO3, off the morphotropic phase boundary of the parent matrix 0.8Bi1/2Na1/2TiO3–0.2Bi1/2K1/2TiO3, has been developed for application as a high-temperature capacitor. In addition to temperature-dependent permittivity and dielectric loss, DC conductivity and field-dependent permittivity are reported. These properties are correlated with temperature-dependent structure data measured at different length scales using Raman spectroscopy and neutron diffraction. It is suggested that all materials investigated are ergodic relaxors with two types of polar nanoregions providing different relaxation mechanisms. The most attractive properties for application as high-temperature dielectrics are obtained in a material with x = 0.15 at less than 10% variation of relative permittivity of about 2100 between 54°C and 400°C. |
| Additional Information: | SFB 595 A1 |
| Divisions: | 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis > Subproject A1: Manufacturing of ceramic, textured actuators with high strain 11 Department of Materials and Earth Sciences > Material Science DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue 11 Department of Materials and Earth Sciences Zentrale Einrichtungen DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres DFG-Collaborative Research Centres (incl. Transregio) |
| Date Deposited: | 18 Sep 2012 08:24 |
| Last Modified: | 05 Mar 2013 10:03 |
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