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Structure and the Electrical Properties of Pb(Zr,Ti)O3 - Zirconia Composites

Benčan, Andreja ; Malič, Barbara ; Drnovšek, Silvo ; Tellier, Jenny ; Rojac, Tadej ; Pavlič, Jernej ; Kosec, Marija ; Webber, Kyle G. ; Rödel, Jürgen ; Damjanovic, Dragan ; Jones, J. L. (2012)
Structure and the Electrical Properties of Pb(Zr,Ti)O3 - Zirconia Composites.
In: Journal of the American Ceramic Society, 95 (2)
doi: 10.1111/j.1551-2916.2011.04803.x
Article, Bibliographie

Abstract

In this work, the effect of introducing tetragonal yttria-stabilized zirconia (TZ) particles in soft [Pb0.98Ba0.01][(Zr0.53Ti0.47)0.98Nb0.02]O3 (PZT) was investigated. Both microstructure and electrical properties of the PZT–xTZ (x = 0, 2, 5, 10, 20 vol%) composites were studied and correlated. The addition of zirconia hinders the matrix grain growth, resulting in smaller grains. According to X-ray diffraction analysis, zirconia containing composites have a higher rhombohedral-to-tetragonal phase ratio, in addition to lower dielectric and piezoelectric properties, in comparison to pure PZT. Electrical properties, in terms of strain– and polarization–electric field hysteresis curves, are presented and correlated with the observed phase compositions and microstructures. The extrinsic contribution to the piezoelectric properties in PZT and PZT–xTZ was studied by measuring the frequency and the stress field amplitude dependences of the piezoelectric d33 coefficient.

Item Type: Article
Erschienen: 2012
Creators: Benčan, Andreja ; Malič, Barbara ; Drnovšek, Silvo ; Tellier, Jenny ; Rojac, Tadej ; Pavlič, Jernej ; Kosec, Marija ; Webber, Kyle G. ; Rödel, Jürgen ; Damjanovic, Dragan ; Jones, J. L.
Type of entry: Bibliographie
Title: Structure and the Electrical Properties of Pb(Zr,Ti)O3 - Zirconia Composites
Language: English
Date: February 2012
Journal or Publication Title: Journal of the American Ceramic Society
Volume of the journal: 95
Issue Number: 2
DOI: 10.1111/j.1551-2916.2011.04803.x
Abstract:

In this work, the effect of introducing tetragonal yttria-stabilized zirconia (TZ) particles in soft [Pb0.98Ba0.01][(Zr0.53Ti0.47)0.98Nb0.02]O3 (PZT) was investigated. Both microstructure and electrical properties of the PZT–xTZ (x = 0, 2, 5, 10, 20 vol%) composites were studied and correlated. The addition of zirconia hinders the matrix grain growth, resulting in smaller grains. According to X-ray diffraction analysis, zirconia containing composites have a higher rhombohedral-to-tetragonal phase ratio, in addition to lower dielectric and piezoelectric properties, in comparison to pure PZT. Electrical properties, in terms of strain– and polarization–electric field hysteresis curves, are presented and correlated with the observed phase compositions and microstructures. The extrinsic contribution to the piezoelectric properties in PZT and PZT–xTZ was studied by measuring the frequency and the stress field amplitude dependences of the piezoelectric d33 coefficient.

Divisions: 11 Department of Materials and Earth Sciences
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences > Material Science > Elektromechanik von Oxiden
11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials
Date Deposited: 10 Feb 2012 09:06
Last Modified: 14 Sep 2021 09:41
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