Daniels, John E. ; Jo, Wook ; Rödel, Jürgen ; Rytz, Daniel ; Donner, Wolfgang (2011)
Structural origins of relaxor behavior in a 0.96(Bi[sub 1/2]Na[sub 1/2])TiO[sub 3]–0.04BaTiO[sub 3] single crystal under electric field.
In: Applied Physics Letters, 98 (25)
doi: 10.1063/1.3602316
Article, Bibliographie
Abstract
Diffuse x-ray scattering intensities from a single crystal of 0.96(Bi1/2Na1/2TiO3)–0.04(BaTiO3) have been collected at room temperature with and without application of an electric field along the [100] direction. Distinct features in the diffuse scattering intensities indicate correlations on a nanometer length scale. It is shown that locally correlated planar-like structures and octahedral tilt-domains within the room temperature rhombohedral R3c phase are both electrically active and are irreversibly affected by application of an electric field of 4.3 kV/mm. The field dependence of these nanoscale structures is correlated with the relaxor behavior of the material by macroscopic permittivity measurements.
Item Type: | Article |
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Erschienen: | 2011 |
Creators: | Daniels, John E. ; Jo, Wook ; Rödel, Jürgen ; Rytz, Daniel ; Donner, Wolfgang |
Type of entry: | Bibliographie |
Title: | Structural origins of relaxor behavior in a 0.96(Bi[sub 1/2]Na[sub 1/2])TiO[sub 3]–0.04BaTiO[sub 3] single crystal under electric field |
Language: | English |
Date: | June 2011 |
Journal or Publication Title: | Applied Physics Letters |
Volume of the journal: | 98 |
Issue Number: | 25 |
DOI: | 10.1063/1.3602316 |
Abstract: | Diffuse x-ray scattering intensities from a single crystal of 0.96(Bi1/2Na1/2TiO3)–0.04(BaTiO3) have been collected at room temperature with and without application of an electric field along the [100] direction. Distinct features in the diffuse scattering intensities indicate correlations on a nanometer length scale. It is shown that locally correlated planar-like structures and octahedral tilt-domains within the room temperature rhombohedral R3c phase are both electrically active and are irreversibly affected by application of an electric field of 4.3 kV/mm. The field dependence of these nanoscale structures is correlated with the relaxor behavior of the material by macroscopic permittivity measurements. |
Uncontrolled Keywords: | barium compounds, bismuth compounds, dielectric polarisation, nanostructured materials, permittivity, relaxor ferroelectrics, sodium compounds, X-ray scattering |
Additional Information: | SFB 595 Cooperation A1, B3 |
Divisions: | 11 Department of Materials and Earth Sciences 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials Zentrale Einrichtungen DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis > Subproject A1: Manufacturing of ceramic, textured actuators with high strain DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > B - Characterisation > Subproject B3: Structure Characterization of Piezoelectric Ceramics With Respect to Electrical Fatigue DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > B - Characterisation DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres DFG-Collaborative Research Centres (incl. Transregio) |
Date Deposited: | 05 Jul 2011 13:26 |
Last Modified: | 05 Mar 2013 09:50 |
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