Zhang, Shan-Tao ; Kounga, Alain Brice ; Aulbach, Emil ; Jo, Wook ; Granzow, Torsten ; Ehrenberg, Helmut ; Rödel, Jürgen (2008)
Lead-free piezoceramics with giant strain in the system Bi[sub 0.5]Na[sub 0.5]TiO[sub 3]–BaTiO[sub 3]–K[sub 0.5]Na[sub 0.5]NbO[sub 3]. II. Temperature dependent properties.
In: Journal of Applied Physics, 103 (3)
doi: 10.1063/1.2838476
Article, Bibliographie

Abstract

The temperature dependence of the dielectric and ferroelectric properties of lead-free piezoceramics of the composition (1−x−y)Bi0.5Na0.5TiO3–xBaTiO3–yK0.5Na0.5NbO3 (0.05 <= x <= 0.07, 0.01 <= y <= 0.03) was investigated. Measurements of the polarization and strain hystereses indicate a transition to predominantly antiferroelectric order when heating from room temperature to 150 °C, while for 150<T<200 °C both remnant polarization and coercive field increase. Frequency-dependent susceptibility measurements show that the transition is relaxorlike. For some samples, the transition temperature Td is high enough to allow mostly ferroelectric ordering at room temperature. These samples show a drastic increase of the usable strain under an external electric field just after the transition into the antiferroelectric state at high temperatures. For the other samples, Td is so low that they display significant antiferroelectric ordering already at room temperature. In these samples, the usable strain is relatively stable over a wide temperature range. In contrast to Td, the temperature Tm of the transition into the paraelectric high-temperature phase depends far less on the sample composition. These results confirm that the high strain in this lead-free system is due to a field-induced antiferroelectric-ferroelectric phase transition and that this effect can be utilized in a wide temperature range.

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