Gaube, Johann ; Klein, Hans-Friedrich (2010)
Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis.
In: Applied Catalysis A: General, 374 (1-2)
Article
Abstract
The recently proposed hypothesis of two incompatible mechanisms of chain growth based on CH₂- and CO-insertion is furthermore supported by a detailed interpretation of the ¹³CH₂N₂ co-feeding experiments of Maitlis and co-workers and of the selectivity of branched hydrocarbons.
The carbon number distribution is discussed considering in particular the role of readsorption and incorporation of 1-alkenes and its subsequent chain growth.
| Item Type: | Article |
|---|---|
| Erschienen: | 2010 |
| Creators: | Gaube, Johann ; Klein, Hans-Friedrich |
| Type of entry: | Bibliographie |
| Title: | Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis |
| Language: | English |
| Date: | 1 February 2010 |
| Journal or Publication Title: | Applied Catalysis A: General |
| Volume of the journal: | 374 |
| Issue Number: | 1-2 |
| URL / URN: | http://dx.doi.org/10.1016/j.apcata.2009.11.039 |
| Abstract: | The recently proposed hypothesis of two incompatible mechanisms of chain growth based on CH₂- and CO-insertion is furthermore supported by a detailed interpretation of the ¹³CH₂N₂ co-feeding experiments of Maitlis and co-workers and of the selectivity of branched hydrocarbons. The carbon number distribution is discussed considering in particular the role of readsorption and incorporation of 1-alkenes and its subsequent chain growth. |
| Identification Number: | doi:10.1016/j.apcata.2009.11.039 |
| Divisions: | 07 Department of Chemistry > Fachgebiet Anorganische Chemie 07 Department of Chemistry > Fachgebiet Technische Chemie 07 Department of Chemistry |
| Date Deposited: | 10 Jan 2011 12:30 |
| Last Modified: | 05 Mar 2013 09:44 |
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