Schimpf, Sabine ; Bron, Michael ; Claus, Peter (2004)
Carbon-coated microstructured reactors for heterogeneously catalyzed gas phase reactions: influence of coating procedure on catalytic activity and selectivity.
In: Chemical Engineering Journal, 101 (1-3)
doi: 10.1016/j.cej.2003.11.009
Article, Bibliographie
Abstract
Carbon-coated microstructures have been prepared via carbonization of polymers, which have been deposited onto microstructured wafers. The amount of carbon deposited depends on the composition of the precursor monomer solution and on the presence of a template. The activity of the wafers after impregnation with ruthenium in the hydrogenation of acrolein is, among others, affected by the composition of the polymers and the time of the calcination step. Most likely, the number of functional groups at the carbon surface as well as the porosity are responsible for this behavior. The selectivity pattern in the hydrogenation of acrolein is similar to that of the acrolein hydrogenation using conventional Ru/C catalysts in a fixed-bed reactor.
| Item Type: | Article |
|---|---|
| Erschienen: | 2004 |
| Creators: | Schimpf, Sabine ; Bron, Michael ; Claus, Peter |
| Type of entry: | Bibliographie |
| Title: | Carbon-coated microstructured reactors for heterogeneously catalyzed gas phase reactions: influence of coating procedure on catalytic activity and selectivity |
| Language: | English |
| Date: | 2004 |
| Journal or Publication Title: | Chemical Engineering Journal |
| Volume of the journal: | 101 |
| Issue Number: | 1-3 |
| DOI: | 10.1016/j.cej.2003.11.009 |
| Abstract: | Carbon-coated microstructures have been prepared via carbonization of polymers, which have been deposited onto microstructured wafers. The amount of carbon deposited depends on the composition of the precursor monomer solution and on the presence of a template. The activity of the wafers after impregnation with ruthenium in the hydrogenation of acrolein is, among others, affected by the composition of the polymers and the time of the calcination step. Most likely, the number of functional groups at the carbon surface as well as the porosity are responsible for this behavior. The selectivity pattern in the hydrogenation of acrolein is similar to that of the acrolein hydrogenation using conventional Ru/C catalysts in a fixed-bed reactor. |
| Uncontrolled Keywords: | Carbon coating; Microstructured reactor; Hydrogenation of acrolein; Carbonization of polymers |
| Divisions: | 07 Department of Chemistry 07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Technische Chemie > Technische Chemie II 07 Department of Chemistry > Ernst-Berl-Institut > Fachgebiet Technische Chemie |
| Date Deposited: | 20 Mar 2009 08:48 |
| Last Modified: | 05 Mar 2013 09:18 |
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