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Biodegradable and bioabsorbable polylactic acid ferroelectrets with prominent piezoelectric activity

Ma, Xingchen ; Zhukov, Sergey ; Seggern, Heinz von ; Sessler, Gerhard M. ; Dali, Omar Ben ; Kupnik, Mario ; Dai, Ying ; He, Pengfei ; Zhang, Xiaoqing (2023)
Biodegradable and bioabsorbable polylactic acid ferroelectrets with prominent piezoelectric activity.
In: Advanced Electronic Materials, 9 (3)
doi: 10.1002/aelm.202201070
Article, Bibliographie

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Abstract

Ferroelectrets have promoted a variety of exciting flexible sensors, actuators, and microenergy harvesters. However, most ferroelectrets have been fabricated from non-degradable petro-based resins, and thus the recycling of these materials constitutes a big challenge. This article reports biodegradable and bioabsorbable ferroelectret films made from polylactic acid (PLA) resins for highly sensitive transducer applications, which can operate either in piezoelectric 33 or 31/32 mode. By modification of the microstructure and polarization, pronounced longitudinal and transverse piezoelectric activities are realized in a single material. For samples with a thickness of 400 µm and a bulk density of 350 kg m⁻³, the Young's moduli in thickness and plane direction are ranging from 0.1 to 10 MPa, respectively. After polarization in the thickness direction, quasi-static piezoelectric d₃₃, g₃₃, d₃₁ (d₃₂), and g₃₁ (g₃₂) coefficients in the PLA films, up to 500 pC N⁻¹, 40 Vm N⁻¹, −44 pC N⁻¹, and −3.6 Vm N⁻¹, are achieved, respectively. The longitudinal piezoelectric coefficients of the PLA films are comparable to non-degradable polymer ferroelectrets, while the transverse piezoelectric activity is superior, which may be attributed to the reduction of Young's moduli in the plane direction. The preparation procedure of the PLA ferroelectrets is compatible with large-scale production lines and thus can greatly promote their applications in green electronics.

Item Type: Article
Erschienen: 2023
Creators: Ma, Xingchen ; Zhukov, Sergey ; Seggern, Heinz von ; Sessler, Gerhard M. ; Dali, Omar Ben ; Kupnik, Mario ; Dai, Ying ; He, Pengfei ; Zhang, Xiaoqing
Type of entry: Bibliographie
Title: Biodegradable and bioabsorbable polylactic acid ferroelectrets with prominent piezoelectric activity
Language: English
Date: 3 January 2023
Place of Publication: Weinheim
Publisher: Wiley
Journal or Publication Title: Advanced Electronic Materials
Volume of the journal: 9
Issue Number: 3
Collation: 10 Seiten
DOI: 10.1002/aelm.202201070
Corresponding Links:
Abstract:

Ferroelectrets have promoted a variety of exciting flexible sensors, actuators, and microenergy harvesters. However, most ferroelectrets have been fabricated from non-degradable petro-based resins, and thus the recycling of these materials constitutes a big challenge. This article reports biodegradable and bioabsorbable ferroelectret films made from polylactic acid (PLA) resins for highly sensitive transducer applications, which can operate either in piezoelectric 33 or 31/32 mode. By modification of the microstructure and polarization, pronounced longitudinal and transverse piezoelectric activities are realized in a single material. For samples with a thickness of 400 µm and a bulk density of 350 kg m⁻³, the Young's moduli in thickness and plane direction are ranging from 0.1 to 10 MPa, respectively. After polarization in the thickness direction, quasi-static piezoelectric d₃₃, g₃₃, d₃₁ (d₃₂), and g₃₁ (g₃₂) coefficients in the PLA films, up to 500 pC N⁻¹, 40 Vm N⁻¹, −44 pC N⁻¹, and −3.6 Vm N⁻¹, are achieved, respectively. The longitudinal piezoelectric coefficients of the PLA films are comparable to non-degradable polymer ferroelectrets, while the transverse piezoelectric activity is superior, which may be attributed to the reduction of Young's moduli in the plane direction. The preparation procedure of the PLA ferroelectrets is compatible with large-scale production lines and thus can greatly promote their applications in green electronics.

Identification Number: Artikel-ID: 2201070
Classification DDC: 600 Technology, medicine, applied sciences > 621.3 Electrical engineering, electronics
Divisions: 11 Department of Materials and Earth Sciences
11 Department of Materials and Earth Sciences > Material Science
18 Department of Electrical Engineering and Information Technology
18 Department of Electrical Engineering and Information Technology > Measurement and Sensor Technology
Date Deposited: 11 Sep 2024 08:57
Last Modified: 11 Sep 2024 12:49
PPN: 521333784
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