Buntkowsky, Gerd ; Döller, Sonja ; Haro-Mares, Nadia ; Gutmann, Torsten ; Hoffmann, Markus (2022)
Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica.
In: Zeitschrift für Physikalische Chemie, 236 (6-8)
doi: 10.1515/zpch-2021-3132
Article, Bibliographie
This is the latest version of this item.
Abstract
This review gives an overview of current trends in the investigation of confined molecules such as higher alcohols, ethylene glycol and polyethylene glycol as guest molecules in neat and functionalized mesoporous silica materials. All these molecules have both hydrophobic and hydrophilic parts. They are characteristic role-models for the investigation of confined surfactants. Their properties are studied by a combination of solid-state NMR and relaxometry with other physicochemical techniques and molecular dynamics techniques. It is shown that this combination delivers unique insights into the structure, arrangement, dynamical properties and the guest-host interactions inside the confinement.
Item Type: | Article |
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Erschienen: | 2022 |
Creators: | Buntkowsky, Gerd ; Döller, Sonja ; Haro-Mares, Nadia ; Gutmann, Torsten ; Hoffmann, Markus |
Type of entry: | Bibliographie |
Title: | Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica |
Language: | English |
Date: | 2022 |
Place of Publication: | Darmstadt |
Publisher: | De Gruyter |
Journal or Publication Title: | Zeitschrift für Physikalische Chemie |
Volume of the journal: | 236 |
Issue Number: | 6-8 |
DOI: | 10.1515/zpch-2021-3132 |
Corresponding Links: | |
Abstract: | This review gives an overview of current trends in the investigation of confined molecules such as higher alcohols, ethylene glycol and polyethylene glycol as guest molecules in neat and functionalized mesoporous silica materials. All these molecules have both hydrophobic and hydrophilic parts. They are characteristic role-models for the investigation of confined surfactants. Their properties are studied by a combination of solid-state NMR and relaxometry with other physicochemical techniques and molecular dynamics techniques. It is shown that this combination delivers unique insights into the structure, arrangement, dynamical properties and the guest-host interactions inside the confinement. |
Uncontrolled Keywords: | confinement, dynamic nuclear polarization (DNP), green solvents, host-guest interactions, solid-state NMR, surfactants |
Classification DDC: | 500 Science and mathematics > 530 Physics 500 Science and mathematics > 540 Chemistry |
Divisions: | 07 Department of Chemistry 07 Department of Chemistry > Eduard Zintl-Institut 07 Department of Chemistry > Eduard Zintl-Institut > Physical Chemistry |
Date Deposited: | 02 Aug 2024 12:53 |
Last Modified: | 02 Aug 2024 12:53 |
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Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica. (deposited 12 Jul 2023 13:05)
- Solid-state NMR studies of non-ionic surfactants confined in mesoporous silica. (deposited 02 Aug 2024 12:53) [Currently Displayed]
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