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Synthesis and Rearrangement of Azulenesulfonium Salts

Müller, Manfred ; Braun, Siegmar ; Hafner, Klaus (1980)
Synthesis and Rearrangement of Azulenesulfonium Salts.
In: Angewandte Chemie International Edition, 19 (8)
doi: 10.1002/anie.198006211
Article, Bibliographie

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Abstract

4-Functionalized azulenes have become accessible via the sulfonium salt (1), X = SMe₂⁺BF₄⁻. On rearrangement of this salt to (3) the dihydro derivative (2) can be isolated, whose formation is of interest in connection with the Sommelet rearrangement.

Item Type: Article
Erschienen: 1980
Creators: Müller, Manfred ; Braun, Siegmar ; Hafner, Klaus
Type of entry: Bibliographie
Title: Synthesis and Rearrangement of Azulenesulfonium Salts
Language: English
Date: 1980
Place of Publication: Darmstadt
Publisher: Wiley
Journal or Publication Title: Angewandte Chemie International Edition
Volume of the journal: 19
Issue Number: 8
DOI: 10.1002/anie.198006211
Corresponding Links:
Abstract:

4-Functionalized azulenes have become accessible via the sulfonium salt (1), X = SMe₂⁺BF₄⁻. On rearrangement of this salt to (3) the dihydro derivative (2) can be isolated, whose formation is of interest in connection with the Sommelet rearrangement.

Classification DDC: 500 Science and mathematics > 540 Chemistry
Divisions: 07 Department of Chemistry
07 Department of Chemistry > Clemens-Schöpf-Institut
07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry
Date Deposited: 02 Aug 2024 12:51
Last Modified: 02 Aug 2024 12:51
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