Bauer, W. ; Hafner, Klaus (1969)
Synthesis and Reactions of a 2H-Azirine Unsubstituted on C–3.
In: Angewandte Chemie International Edition, 8 (10)
doi: 10.1002/anie.196907721
Article, Bibliographie
This is the latest version of this item.
Abstract
Thermolysis [¹] or photolysis [²] of 1-alkyl or 1-aryl-vinyl azides (1) (R¹ = R² = H, aryl, alkyl; R³= aryl, alkyl)[³] leads to the formation of 2H-azirines with a substituent at C-3 (2) and to ketenimines (3). However, the decomposition of “terminal” vinyl azides (1) (R¹ = R² == H, aryl, alkyl; R³ = H) gives only the nitriles (4) [⁴] and none of the expected, and formerly unknown, 2H-azirines which lack a substituent at the 3-position.
| Item Type: | Article |
|---|---|
| Erschienen: | 1969 |
| Creators: | Bauer, W. ; Hafner, Klaus |
| Type of entry: | Bibliographie |
| Title: | Synthesis and Reactions of a 2H-Azirine Unsubstituted on C–3 |
| Language: | English |
| Date: | 1969 |
| Place of Publication: | Darmstadt |
| Publisher: | Wiley |
| Journal or Publication Title: | Angewandte Chemie International Edition |
| Volume of the journal: | 8 |
| Issue Number: | 10 |
| DOI: | 10.1002/anie.196907721 |
| Corresponding Links: | |
| Abstract: | Thermolysis [¹] or photolysis [²] of 1-alkyl or 1-aryl-vinyl azides (1) (R¹ = R² = H, aryl, alkyl; R³= aryl, alkyl)[³] leads to the formation of 2H-azirines with a substituent at C-3 (2) and to ketenimines (3). However, the decomposition of “terminal” vinyl azides (1) (R¹ = R² == H, aryl, alkyl; R³ = H) gives only the nitriles (4) [⁴] and none of the expected, and formerly unknown, 2H-azirines which lack a substituent at the 3-position. |
| Classification DDC: | 500 Science and mathematics > 540 Chemistry |
| Divisions: | 07 Department of Chemistry 07 Department of Chemistry > Clemens-Schöpf-Institut 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry |
| Date Deposited: | 02 Aug 2024 12:45 |
| Last Modified: | 02 Aug 2024 12:45 |
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| Suche nach Titel in: | TUfind oder in Google |
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Synthesis and Reactions of a 2H-Azirine Unsubstituted on C–3. (deposited 22 Nov 2022 09:47)
- Synthesis and Reactions of a 2H-Azirine Unsubstituted on C–3. (deposited 02 Aug 2024 12:45) [Currently Displayed]
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