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Band offsets at the ZnSe/CuGaSe₂(001) heterointerface

Bauknecht, Andreas ; Blieske, U. ; Kampschulte, T. ; Albert, J. ; Sehnert, H. ; Lux-Steiner, Martha Ch. ; Klein, Andreas ; Jaegermann, Wolfram (1999)
Band offsets at the ZnSe/CuGaSe₂(001) heterointerface.
In: Applied Physics Letters, 74 (8)
doi: 10.1063/1.123455
Article, Bibliographie

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Abstract

The formation of the ZnSe/CuGaSe₂ heterointerface was studied by x-ray photoelectron spectroscopy (XPS). ZnSe was sequentially grown on CuGaSe₂(001) epilayers. In situ photoemission spectra of the Ga 3d and Zn 3d core levels as well as XPS valence bands were acquired after each deposition step. The valence-band offset is determined to be ΔEV=0.6±0.1 eV. As a consequence, a nearly symmetric "type-I" band alignment for the ZnSe/CuGaSe₂ heterojunction with a conduction-band offset of ΔEC=0.4±0.1 eV is found. Concerning the band alignment ZnSe can, therefore, be expected to be a suitable buffer material for CuGaSe₂-based thin-film solar cells.

Item Type: Article
Erschienen: 1999
Creators: Bauknecht, Andreas ; Blieske, U. ; Kampschulte, T. ; Albert, J. ; Sehnert, H. ; Lux-Steiner, Martha Ch. ; Klein, Andreas ; Jaegermann, Wolfram
Type of entry: Bibliographie
Title: Band offsets at the ZnSe/CuGaSe₂(001) heterointerface
Language: English
Date: 1999
Publisher: AIP Publishing
Journal or Publication Title: Applied Physics Letters
Volume of the journal: 74
Issue Number: 8
DOI: 10.1063/1.123455
Corresponding Links:
Abstract:

The formation of the ZnSe/CuGaSe₂ heterointerface was studied by x-ray photoelectron spectroscopy (XPS). ZnSe was sequentially grown on CuGaSe₂(001) epilayers. In situ photoemission spectra of the Ga 3d and Zn 3d core levels as well as XPS valence bands were acquired after each deposition step. The valence-band offset is determined to be ΔEV=0.6±0.1 eV. As a consequence, a nearly symmetric "type-I" band alignment for the ZnSe/CuGaSe₂ heterojunction with a conduction-band offset of ΔEC=0.4±0.1 eV is found. Concerning the band alignment ZnSe can, therefore, be expected to be a suitable buffer material for CuGaSe₂-based thin-film solar cells.

Classification DDC: 500 Science and mathematics > 530 Physics
Divisions: 11 Department of Materials and Earth Sciences
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences > Material Science > Surface Science
Date Deposited: 02 Aug 2024 12:37
Last Modified: 02 Aug 2024 12:37
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