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Acid Neutralization Capacity of Metakaolin‐based Geopolymers

Ukrainczyk, Neven ; Koenders, Eddie (2023)
Acid Neutralization Capacity of Metakaolin‐based Geopolymers.
In: ce/papers : Proceedings in Civil Engineering, 6 (6)
doi: 10.1002/cepa.2994
Article, Bibliographie

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Abstract

A titration method is used to analyse the acid neutralization/consumption capacity (ANC) of cement binders, which involves plotting the steady‐state pH against the amount of acid added to a diluted suspension of hardened cement samples. Despite ANC being employed for several decades, there is no reported application of ANC for metakaolin‐based geopolymers. This study compares the resistance of metakaolin geopolymers to acetic acid and hydrochloric acid with that of Calcium Aluminate Cement (CAC) and Portland Cement (PC). The proposed ANC test setup involves small acid dosage steps using an auto‐titrator, resulting in a high‐resolution titration curve. The effect of binder chemical composition on acid resistance is evaluated through cumulative and differential ANC analysis, providing a new rapid approach to evaluate the durability of geopolymers in low pH environments.

Item Type: Article
Erschienen: 2023
Creators: Ukrainczyk, Neven ; Koenders, Eddie
Type of entry: Bibliographie
Title: Acid Neutralization Capacity of Metakaolin‐based Geopolymers
Language: English
Date: December 2023
Place of Publication: Berlin
Publisher: Ernst & Sohn, a Wiley brand
Journal or Publication Title: ce/papers : Proceedings in Civil Engineering
Volume of the journal: 6
Issue Number: 6
DOI: 10.1002/cepa.2994
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Abstract:

A titration method is used to analyse the acid neutralization/consumption capacity (ANC) of cement binders, which involves plotting the steady‐state pH against the amount of acid added to a diluted suspension of hardened cement samples. Despite ANC being employed for several decades, there is no reported application of ANC for metakaolin‐based geopolymers. This study compares the resistance of metakaolin geopolymers to acetic acid and hydrochloric acid with that of Calcium Aluminate Cement (CAC) and Portland Cement (PC). The proposed ANC test setup involves small acid dosage steps using an auto‐titrator, resulting in a high‐resolution titration curve. The effect of binder chemical composition on acid resistance is evaluated through cumulative and differential ANC analysis, providing a new rapid approach to evaluate the durability of geopolymers in low pH environments.

Uncontrolled Keywords: Acid neutralisation capacity, Geopolymers, Metakaolin, Calcium Aluminate Cement, Portland Cement, Acid Attack
Classification DDC: 600 Technology, medicine, applied sciences > 624 Civil engineering and environmental protection engineering
Divisions: 13 Department of Civil and Environmental Engineering Sciences
13 Department of Civil and Environmental Engineering Sciences > Institute of Construction and Building Materials
Date Deposited: 28 May 2024 08:37
Last Modified: 28 May 2024 08:37
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