Ukrainczyk, Neven ; Muthu, Murugan ; Vogt, Oliver ; Koenders, Eddie (2024)
Geopolymer, Calcium Aluminate, and Portland Cement-Based Mortars: Comparing Degradation Using Acetic Acid.
In: Materials, 2019, 12 (19)
doi: 10.26083/tuprints-00016237
Article, Secondary publication, Publisher's Version
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Abstract
In this paper, we comparitvley studied acetic acid attacks on geopolymer (GP-M), calcium aluminate (CAC-M), and Portland cement (PC-M)-based mortars. Consequent formations of deteriorated or transition layers surrounding the unaltered core material was classified in these three mortars, according to different degradation levels depending on what binder type was involved. Apart from mass loss, hardness, and deterioration depth, their microstructural alterations were analyzed using test methods such as scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), mercury intrusion porosimetry (MIP), powder X-ray diffraction (XRD), and thermogravimetric analysis-differential scanning calorimeter (TGA-DSC), which showed the different mechanisms for each binder type. Elemental maps revealed the decalcification (PC-M and CAC-M) and depolymerization (GP-M) that occurred across the mortar sections. The mass loss, hardness, and porosity were the least affected for GP-M, followed by CAC-M. These results points out that geopolymer-based mortars have improved acid resistance, which can be used as a potential alternative to conventional cement concretes that have been exposed to agro-industrial environments.
Item Type: | Article |
---|---|
Erschienen: | 2024 |
Creators: | Ukrainczyk, Neven ; Muthu, Murugan ; Vogt, Oliver ; Koenders, Eddie |
Type of entry: | Secondary publication |
Title: | Geopolymer, Calcium Aluminate, and Portland Cement-Based Mortars: Comparing Degradation Using Acetic Acid |
Language: | English |
Date: | 16 January 2024 |
Place of Publication: | Darmstadt |
Year of primary publication: | 2019 |
Place of primary publication: | Basel |
Publisher: | MDPI |
Journal or Publication Title: | Materials |
Volume of the journal: | 12 |
Issue Number: | 19 |
Collation: | 12 Seiten |
DOI: | 10.26083/tuprints-00016237 |
URL / URN: | https://tuprints.ulb.tu-darmstadt.de/16237 |
Corresponding Links: | |
Origin: | Secondary publication DeepGreen |
Abstract: | In this paper, we comparitvley studied acetic acid attacks on geopolymer (GP-M), calcium aluminate (CAC-M), and Portland cement (PC-M)-based mortars. Consequent formations of deteriorated or transition layers surrounding the unaltered core material was classified in these three mortars, according to different degradation levels depending on what binder type was involved. Apart from mass loss, hardness, and deterioration depth, their microstructural alterations were analyzed using test methods such as scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), mercury intrusion porosimetry (MIP), powder X-ray diffraction (XRD), and thermogravimetric analysis-differential scanning calorimeter (TGA-DSC), which showed the different mechanisms for each binder type. Elemental maps revealed the decalcification (PC-M and CAC-M) and depolymerization (GP-M) that occurred across the mortar sections. The mass loss, hardness, and porosity were the least affected for GP-M, followed by CAC-M. These results points out that geopolymer-based mortars have improved acid resistance, which can be used as a potential alternative to conventional cement concretes that have been exposed to agro-industrial environments. |
Uncontrolled Keywords: | geopolymer, Portland cement, calcium aluminate cement, leaching, microstructure, deterioration, acetic acid attack, SEM-EDS |
Status: | Publisher's Version |
URN: | urn:nbn:de:tuda-tuprints-162378 |
Additional Information: | This article belongs to the Section Construction and Building Materials |
Classification DDC: | 600 Technology, medicine, applied sciences > 624 Civil engineering and environmental protection engineering 600 Technology, medicine, applied sciences > 660 Chemical engineering |
Divisions: | 13 Department of Civil and Environmental Engineering Sciences 13 Department of Civil and Environmental Engineering Sciences > Institute of Construction and Building Materials |
Date Deposited: | 16 Jan 2024 12:13 |
Last Modified: | 17 Jan 2024 14:50 |
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