Porz, Lukas ; Scherer, Michael ; Muhammad, Qaisar Khushi ; Higuchi, Kimitaka ; Li, Yan ; Koga, Shuhei ; Nakamura, Atsutomo ; Rheinheimer, Wolfgang ; Frömling, Till (2022)
Microstructure and conductivity of blacklight‐sintered TiO₂, YSZ, and Li₀.₃₃La₀.₅₇TiO₃.
In: Journal of the American Ceramic Society, 105 (12)
doi: 10.1111/jace.18686
Article, Bibliographie
This is the latest version of this item.
Abstract
Rapid densification of ceramics has been realized and its merits were demonstrated through multiple approaches out of which UHS and flash sintering attract recent attention. So far, however, scalability remains difficult. A rise in throughput and scalability is enabled by the introduction of blacklight sintering powered by novel light source technology. Intense illumination with photon energy above the bandgap (blacklight) allows high absorption efficiency and, hence, very rapid, contactless heating for all ceramics. While heating the ceramic directly with light without any furnace promises scalability, it simultaneously offers highly accurate process control. For the technology transfer to industry, attainable material quality needs to be assured. Here, we demonstrate the excellent microstructure quality of blacklight‐sintered ceramics observed with ultrahigh voltage electron microscopy revealing an option to tune nanoporosity. Moreover, we confirm that electronic, electron, oxygen, and lithium‐ion conductivities are equal to conventionally sintered ceramics. This gives the prospect of transmitting the merits of rapid densification to the scale of industrial kilns.
| Item Type: | Article |
|---|---|
| Erschienen: | 2022 |
| Creators: | Porz, Lukas ; Scherer, Michael ; Muhammad, Qaisar Khushi ; Higuchi, Kimitaka ; Li, Yan ; Koga, Shuhei ; Nakamura, Atsutomo ; Rheinheimer, Wolfgang ; Frömling, Till |
| Type of entry: | Bibliographie |
| Title: | Microstructure and conductivity of blacklight‐sintered TiO₂, YSZ, and Li₀.₃₃La₀.₅₇TiO₃ |
| Language: | English |
| Date: | 2022 |
| Place of Publication: | Darmstadt |
| Publisher: | Wiley |
| Journal or Publication Title: | Journal of the American Ceramic Society |
| Volume of the journal: | 105 |
| Issue Number: | 12 |
| DOI: | 10.1111/jace.18686 |
| Corresponding Links: | |
| Abstract: | Rapid densification of ceramics has been realized and its merits were demonstrated through multiple approaches out of which UHS and flash sintering attract recent attention. So far, however, scalability remains difficult. A rise in throughput and scalability is enabled by the introduction of blacklight sintering powered by novel light source technology. Intense illumination with photon energy above the bandgap (blacklight) allows high absorption efficiency and, hence, very rapid, contactless heating for all ceramics. While heating the ceramic directly with light without any furnace promises scalability, it simultaneously offers highly accurate process control. For the technology transfer to industry, attainable material quality needs to be assured. Here, we demonstrate the excellent microstructure quality of blacklight‐sintered ceramics observed with ultrahigh voltage electron microscopy revealing an option to tune nanoporosity. Moreover, we confirm that electronic, electron, oxygen, and lithium‐ion conductivities are equal to conventionally sintered ceramics. This gives the prospect of transmitting the merits of rapid densification to the scale of industrial kilns. |
| Uncontrolled Keywords: | blacklight sintering, conductivity, microstructure, sinter/sintering |
| Classification DDC: | 600 Technology, medicine, applied sciences > 660 Chemical engineering |
| Divisions: | 11 Department of Materials and Earth Sciences 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials |
| Date Deposited: | 06 Dec 2023 09:52 |
| Last Modified: | 06 Dec 2023 09:52 |
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| Suche nach Titel in: | TUfind oder in Google |
Available Versions of this Item
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Microstructure and conductivity of blacklight‐sintered TiO₂, YSZ, and Li₀.₃₃La₀.₅₇TiO₃. (deposited 28 Nov 2022 14:08)
- Microstructure and conductivity of blacklight‐sintered TiO₂, YSZ, and Li₀.₃₃La₀.₅₇TiO₃. (deposited 06 Dec 2023 09:52) [Currently Displayed]
- Microstructure and conductivity of blacklight-sinteredTiO2, YSZ, and Li0.33La0.57TiO3. (deposited 05 Oct 2022 05:51)
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