Beckmann, Benedikt ; Koch, David ; Pfeuffer, Lukas ; Gottschall, Tino ; Taubel, Andreas ; Adabifiroozjaei, Esmaeil ; Miroshkina, Olga N. ; Riegg, Stefan ; Niehoff, Timo ; Kani, Nagaarjhuna A. ; Gruner, Markus E. ; Molina-Luna, Leopoldo ; Skokov, Konstantin P. ; Gutfleisch, Oliver (2023)
Dissipation losses limiting first-order phase transition materials in cryogenic caloric cooling: A case study on all-d-metal Ni(-Co)-Mn-Ti Heusler alloys.
In: Acta Materialia, 246
doi: 10.1016/j.actamat.2023.118695
Article, Bibliographie

Abstract

Ni-Mn-based Heusler alloys, in particular all-d-metal Ni(-Co)-Mn-Ti, are highly promising materials for energy-efficient solid-state refrigeration as large multicaloric effects can be achieved across their magnetostructural martensitic transformation. However, no comprehensive study on the crucially important transition entropy change exists so far for Ni(-Co)-Mn-Ti. Here, we present a systematic study analyzing the composition and temperature dependence of . Our results reveal a substantial structural entropy change contribution of approximately 65 J(kgK)-1, which is compensated at lower temperatures by an increasingly negative entropy change associated with the magnetic subsystem. This leads to compensation temperatures of 75 K and 300 K in Ni35Co15Mn50-yTiy and Ni33Co17Mn50-yTiy, respectively, below which the martensitic transformations are arrested. In addition, we simultaneously measured the responses of the magnetic, structural and electronic subsystems to the temperature- and field-induced martensitic transformation near , showing an abnormal increase of hysteresis and consequently dissipation energy at cryogenic temperatures. Simultaneous measurements of magnetization and adiabatic temperature change in pulsed magnetic fields reveal a change in sign of and a substantial positive and irreversible up to 15 K at 15 K as a consequence of increased dissipation losses and decreased heat capacity. Most importantly, this phenomenon is universal, it applies to any first-order material with non-negligible hysteresis and any stimulus, effectively limiting the utilization of their caloric effects for gas liquefaction at cryogenic temperatures.

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