Fabian, Kai H. H. ; Lindner, Hans-Jörg ; Nimmerfroh, Norbert ; Hafner, Klaus (2022):
Synthesis and Properties of the First [4.4]Ferrocenophane-1,3,15,17-tetrayne. (Publisher's Version)
In: Angewandte Chemie International Edition, 40 (18), pp. 3402-3405. Wiley, ISSN 1433-7851,
DOI: 10.26083/tuprints-00022368,
[Article]
Abstract
Building butadiyne bridges: The kinetically stabilized 1,1′-diethynylferrocene, readily prepared from the pentafulvenoid allene 1, can be transformed into the [4.4]ferrocenophane 2 by oxidative coupling. This compound exhibits a remarkably symmetrical structure in which the electrons are delocalized through the butadiyne bridges; in the crystalline state 2 exists in a helical-chiral conformation.
| Item Type: | Article |
|---|---|
| Erschienen: | 2022 |
| Creators: | Fabian, Kai H. H. ; Lindner, Hans-Jörg ; Nimmerfroh, Norbert ; Hafner, Klaus |
| Origin: | Secondary publication service |
| Status: | Publisher's Version |
| Title: | Synthesis and Properties of the First [4.4]Ferrocenophane-1,3,15,17-tetrayne |
| Language: | English |
| Abstract: | Building butadiyne bridges: The kinetically stabilized 1,1′-diethynylferrocene, readily prepared from the pentafulvenoid allene 1, can be transformed into the [4.4]ferrocenophane 2 by oxidative coupling. This compound exhibits a remarkably symmetrical structure in which the electrons are delocalized through the butadiyne bridges; in the crystalline state 2 exists in a helical-chiral conformation. |
| Journal or Publication Title: | Angewandte Chemie International Edition |
| Volume of the journal: | 40 |
| Issue Number: | 18 |
| Place of Publication: | Darmstadt |
| Publisher: | Wiley |
| Divisions: | 07 Department of Chemistry 07 Department of Chemistry > Organ Chemistry |
| Date Deposited: | 28 Nov 2022 09:05 |
| DOI: | 10.26083/tuprints-00022368 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/22368 |
| URN: | urn:nbn:de:tuda-tuprints-223685 |
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| Corresponding Links: | |
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