Bauer, W. ; Hafner, Klaus (2022)
Synthesis and Reactions of a 2H-Azirine Unsubstituted on C–3.
In: Angewandte Chemie International Edition, 1969, 8 (10)
doi: 10.26083/tuprints-00022293
Article, Secondary publication, Publisher's Version
There is a more recent version of this item available. |
Abstract
Thermolysis [¹] or photolysis [²] of 1-alkyl or 1-aryl-vinyl azides (1) (R¹ = R² = H, aryl, alkyl; R³= aryl, alkyl)[³] leads to the formation of 2H-azirines with a substituent at C-3 (2) and to ketenimines (3). However, the decomposition of “terminal” vinyl azides (1) (R¹ = R² == H, aryl, alkyl; R³ = H) gives only the nitriles (4) [⁴] and none of the expected, and formerly unknown, 2H-azirines which lack a substituent at the 3-position.
Item Type: | Article |
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Erschienen: | 2022 |
Creators: | Bauer, W. ; Hafner, Klaus |
Type of entry: | Secondary publication |
Title: | Synthesis and Reactions of a 2H-Azirine Unsubstituted on C–3 |
Language: | English |
Date: | 2022 |
Place of Publication: | Darmstadt |
Year of primary publication: | 1969 |
Publisher: | Wiley |
Journal or Publication Title: | Angewandte Chemie International Edition |
Volume of the journal: | 8 |
Issue Number: | 10 |
DOI: | 10.26083/tuprints-00022293 |
URL / URN: | https://tuprints.ulb.tu-darmstadt.de/22293 |
Corresponding Links: | |
Origin: | Secondary publication service |
Abstract: | Thermolysis [¹] or photolysis [²] of 1-alkyl or 1-aryl-vinyl azides (1) (R¹ = R² = H, aryl, alkyl; R³= aryl, alkyl)[³] leads to the formation of 2H-azirines with a substituent at C-3 (2) and to ketenimines (3). However, the decomposition of “terminal” vinyl azides (1) (R¹ = R² == H, aryl, alkyl; R³ = H) gives only the nitriles (4) [⁴] and none of the expected, and formerly unknown, 2H-azirines which lack a substituent at the 3-position. |
Status: | Publisher's Version |
URN: | urn:nbn:de:tuda-tuprints-222938 |
Classification DDC: | 500 Science and mathematics > 540 Chemistry |
Divisions: | 07 Department of Chemistry 07 Department of Chemistry > Clemens-Schöpf-Institut 07 Department of Chemistry > Clemens-Schöpf-Institut > Organ Chemistry |
Date Deposited: | 22 Nov 2022 09:47 |
Last Modified: | 02 Aug 2024 12:45 |
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