Pan, Zhao ; Zhang, Mao-Hua ; Nishikubo, Takumi ; Sakai, Yuki ; Yamamoto, Hajime ; Hojo, Hajime ; Fukuda, Masayuki ; Hu, Lei ; Ishizaki, Hayato ; Kaneko, Satoru ; Kawaguchi, Shogo ; Koruza, Jurij ; Rödel, Jürgen ; Azuma, Masaki (2021)
Polarization Rotation at Morphotropic Phase Boundary in New Lead-Free Na1/2Bi1/2V1−xTixO3 Piezoceramics.
In: ACS Applied Materials & Interfaces, 13 (4)
doi: 10.1021/acsami.0c18482
Article, Bibliographie

Abstract

In this work, we show that polarization rotation enhances the piezoresponse in a high-performance lead-free piezoelectric material, Na1/2Bi1/2V1−xTixO3, a solid solution between tetragonal Na1/2Bi1/2VO3 and rhombohedral Na1/2Bi1/2TiO3, obtained by high-pressure synthesis. The system forms a pure perovskite structure with a favorable morphotropic phase boundary (MPB) located around x = 0.90, which separates the tetragonal and rhombohedral phases. In addition, a distinct monoclinic phase with polarization rotation as functions of composition and temperature is observed. XRD measurements revealed the moderately high Curie temperature of 523 K at x = 0.95 in the MPB. The piezoelectric coefficient d33 of the monoclinic x = 0.95 sample, 42 pC/N, is higher than those of the tetragonal and rhombohedral phases. Even though the present lead-free Na1/2Bi1/2V1−xTixO3 ceramics feature smaller d33 values compared to many currently available lead-free piezoelectric materials as a result of insufficient poling and low density, we expect our findings open up opportunities for exploring promising lead-free piezoelectric materials in Na1/2Bi1/2VO3-based perovskites.

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