Chavez, Ricardo ; Ionescu, Emanuel ; Fasel, Claudia ; Riedel, Ralf (2013)
Imide-containing ladder polyphenylsilsesquioxanes with high thermal stability and thermoplastic properties.
In: Journal of Applied Polymer Science, 131 (7)
doi: 10.1002/app.40085
Article, Bibliographie
Abstract
This work reports for the first time the synthesis of ladder polyphenylsilsesquioxanes containing imide building blocks as parts of the main parallel chains. The ladder structure of the synthesized polymers was documented by means of small angle X‐ray scattering (SAXS) measurements. The obtained ladder polymers exhibit stability with respect to decomposition up to temperatures as high as 460°C; additionally, they have melting points far below their decomposition temperatures, which make them interesting candidate materials for thermoplastic processing. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40085.
| Item Type: | Article |
|---|---|
| Erschienen: | 2013 |
| Creators: | Chavez, Ricardo ; Ionescu, Emanuel ; Fasel, Claudia ; Riedel, Ralf |
| Type of entry: | Bibliographie |
| Title: | Imide-containing ladder polyphenylsilsesquioxanes with high thermal stability and thermoplastic properties |
| Language: | English |
| Date: | 5 April 2013 |
| Publisher: | Wiley-VCH Verlag GmbH, Weinheim |
| Journal or Publication Title: | Journal of Applied Polymer Science |
| Volume of the journal: | 131 |
| Issue Number: | 7 |
| DOI: | 10.1002/app.40085 |
| URL / URN: | https://doi.org/10.1002/app.40085 |
| Abstract: | This work reports for the first time the synthesis of ladder polyphenylsilsesquioxanes containing imide building blocks as parts of the main parallel chains. The ladder structure of the synthesized polymers was documented by means of small angle X‐ray scattering (SAXS) measurements. The obtained ladder polymers exhibit stability with respect to decomposition up to temperatures as high as 460°C; additionally, they have melting points far below their decomposition temperatures, which make them interesting candidate materials for thermoplastic processing. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40085. |
| Uncontrolled Keywords: | polyimides, thermoplastics, inorganic polymers, thermal properties |
| Divisions: | 11 Department of Materials and Earth Sciences 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids |
| Date Deposited: | 17 Dec 2018 13:32 |
| Last Modified: | 17 Dec 2018 13:32 |
| PPN: | |
| Funders: | R.R. thanks the Fonds der Chemische Industrie for continuous financial support. |
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