Serghiou, G. ; Miehe, G. ; Tschauner, O. ; Zerr, A. ; Boehler, R. (1999)
Synthesis of a cubic Ge3N4 phase at high pressures and temperatures.
In: Journal of chemical physics, 111 (10)
Article
Abstract
The two known phases of germanium nitride (Ge3N4) have hexagonal and trigonal symmetries and consist of three-dimensional networks of corner-connected Ge–N tetrahedra. A new cubic spinel phase (space-group Fd3m, a0 = 8.3 Å, Z = 8, ρ = 6.36 g/cm3) containing Ge–N octahedra and tetrahedra in a 2:1 ratio was synthesized from elemental germanium and molecular nitrogen starting materials in a laser-heated diamond-anvil cell above 14 GPa. This phase is isostructural to the recently discovered cubic spinel phase of Si3N4.
| Item Type: | Article |
|---|---|
| Erschienen: | 1999 |
| Creators: | Serghiou, G. ; Miehe, G. ; Tschauner, O. ; Zerr, A. ; Boehler, R. |
| Type of entry: | Bibliographie |
| Title: | Synthesis of a cubic Ge3N4 phase at high pressures and temperatures |
| Language: | English |
| Date: | 8 September 1999 |
| Publisher: | American Institute of Physics |
| Journal or Publication Title: | Journal of chemical physics |
| Volume of the journal: | 111 |
| Issue Number: | 10 |
| Abstract: | The two known phases of germanium nitride (Ge3N4) have hexagonal and trigonal symmetries and consist of three-dimensional networks of corner-connected Ge–N tetrahedra. A new cubic spinel phase (space-group Fd3m, a0 = 8.3 Å, Z = 8, ρ = 6.36 g/cm3) containing Ge–N octahedra and tetrahedra in a 2:1 ratio was synthesized from elemental germanium and molecular nitrogen starting materials in a laser-heated diamond-anvil cell above 14 GPa. This phase is isostructural to the recently discovered cubic spinel phase of Si3N4. |
| Uncontrolled Keywords: | germanium compounds, high-pressure effects, high-temperature effects, chemical reactions |
| Divisions: | 11 Department of Materials and Earth Sciences 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids |
| Date Deposited: | 19 Nov 2008 16:20 |
| Last Modified: | 20 Feb 2020 13:28 |
| PPN: | |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
 |
Send an inquiry |
Options (only for editors)
 |
Show editorial Details |
Drucken
Impressum