Schüth, Christoph ; Reinhard, Martin (1998)
Hydrodechlorination and hydrogenation of aromatic compounds over palladium on alumina in hydrogen-saturated water.
In: Applied Catalysis B: Environmental, 18 (3-4)
doi: 10.1016/S0926-3373(98)00037-X
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
The catalytic transformations of 1,2-dichlorobenzene, chlorobenzene, 4-chlorobiphenyl, γ-hexachlorocyclohexane (Lindane), naphthalene and phenanthrene were studied over palladium on alumina in hydrogen-saturated water (Pd/Al2O3/H2) at room temperature and ambient pressure. The chlorinated benzenes were rapidly hydrodechlorinated and Lindane was dehydrochlorinated to benzene. Partial or complete hydrogenation was observed for biphenyl and the polycyclic aromatic hydrocarbons. The phenanthrene ring was cleaved at the 9,10-position. In general dechlorination reactions were faster than hydrogenation reactions.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 1998 |
| Autor(en): | Schüth, Christoph ; Reinhard, Martin |
| Art des Eintrags: | Bibliographie |
| Titel: | Hydrodechlorination and hydrogenation of aromatic compounds over palladium on alumina in hydrogen-saturated water |
| Sprache: | Englisch |
| Publikationsjahr: | Oktober 1998 |
| Verlag: | Elsevier |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Applied Catalysis B: Environmental |
| Jahrgang/Volume einer Zeitschrift: | 18 |
| (Heft-)Nummer: | 3-4 |
| DOI: | 10.1016/S0926-3373(98)00037-X |
| URL / URN: | https://www.sciencedirect.com/science/article/pii/S092633739... |
| Kurzbeschreibung (Abstract): | The catalytic transformations of 1,2-dichlorobenzene, chlorobenzene, 4-chlorobiphenyl, γ-hexachlorocyclohexane (Lindane), naphthalene and phenanthrene were studied over palladium on alumina in hydrogen-saturated water (Pd/Al2O3/H2) at room temperature and ambient pressure. The chlorinated benzenes were rapidly hydrodechlorinated and Lindane was dehydrochlorinated to benzene. Partial or complete hydrogenation was observed for biphenyl and the polycyclic aromatic hydrocarbons. The phenanthrene ring was cleaved at the 9,10-position. In general dechlorination reactions were faster than hydrogenation reactions. |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften > Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Geowissenschaften > Fachgebiet Hydrogeologie 11 Fachbereich Material- und Geowissenschaften |
| Hinterlegungsdatum: | 17 Apr 2018 11:50 |
| Letzte Änderung: | 17 Apr 2018 11:50 |
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